Theory of Onsager phenomenological coefficients for isothermal linear transport processes in electrolyte solutions

Thomas S. Thacher, Jeong Long Lin, C. Y. Mou

研究成果: 雜誌貢獻文章同行評審

13 引文 斯高帕斯(Scopus)

摘要

The Onsager phenomenological coefficients Lij for linear isothermal transport processes for electrolyte solutions have been calculated from the velocity time-correlation functions. Our approach is based on the assumption that the ionic velocities are evolved by the Fokker-Planck operator. The limiting law expression for Lij has been derived. In addition, numerical calculations using the HNC pair distribution function have been performed for several chloride solutions. The results indicate that our theory can qualitatively describe the experimental values up to a concentration of about 2 M.
原文英語
頁(從 - 到)2053-2063
頁數11
期刊The Journal of Chemical Physics
81
發行號4
DOIs
出版狀態已發佈 - 1984
對外發佈

ASJC Scopus subject areas

  • 物理與天文學 (全部)
  • 物理與理論化學

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