Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C60 adduct

Lung Lin Shiu, Tsung I. Lin, Shie Ming Peng, Guor Rong Her, Dar Der Ju, Syh Kun Lin, Jyun Hwei Hwang, Chung Yuan Mou, Tien Yau Luh

研究成果: 雜誌貢獻文章同行評審

45 引文 斯高帕斯(Scopus)

摘要

The first synthesis of the parent TMM-C60 adduct 1 was achieved by means of Pd°-mediated [3 + 2] cycloaddition and its structure was unambiguously proved by spectroscopic means (1H and 13C NMR and MS); a pentane solution of the adduct 1 exhibited a fluorescence emission spectrum with λmax 704 nm and vibronic fine structure at ambient temperature.

原文英語
頁(從 - 到)647-648
頁數2
期刊Journal of the Chemical Society, Chemical Communications
發行號5
DOIs
出版狀態已發佈 - 1994
對外發佈

ASJC Scopus subject areas

  • 分子醫學

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