Ga-promoted tungstated zirconia catalyst for n-butane isomerization

Xiao Rong Chen; Chang Lin Chen; Nan Ping Xu; Song Han; Chung Yuan Mou

doi:10.1023/A:1022137612328

Ga-promoted tungstated zirconia catalyst for n-butane isomerization

Xiao Rong Chen, Chang Lin Chen, Nan Ping Xu, Song Han, Chung Yuan Mou

研究成果: 雜誌貢獻 › 文章 › 同行評審

22 引文斯高帕斯（Scopus）

摘要

Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N₂ adsorption, NH₃ temperature-programmed desorption (NH₃ TPD), microcalorimetry and H₂ temperature-programmed reduction (H₂ TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.

原文	英語
頁（從 - 到）	177-182
頁數	6
期刊	Catalysis Letters
卷	85
發行號	3-4
DOIs	https://doi.org/10.1023/A:1022137612328
出版狀態	已發佈 - 2月 2003
對外發佈	是

ASJC Scopus subject areas

催化
一般化學

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title = "Ga-promoted tungstated zirconia catalyst for n-butane isomerization",

abstract = "Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N2 adsorption, NH3 temperature-programmed desorption (NH3 TPD), microcalorimetry and H2 temperature-programmed reduction (H2 TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.",

keywords = "Gallium, N-butane isomerization, Tungstated zirconia",

author = "Chen, {Xiao Rong} and Chen, {Chang Lin} and Xu, {Nan Ping} and Song Han and Mou, {Chung Yuan}",

note = "Funding Information: We thank Professor Jianyi Shen from Nanjing University for help in the microcalorimetric study. Financial support from the Educational Department of Jiangsu Province (Project 00KJB530001 to CLC), the Science and Technology Department of Jiangsu Province (Project GB2002017 to CLC), and Key Laboratory of Chemical Engineering and Technology of Jiangsu Province is gratefully acknowledged.",

year = "2003",

month = feb,

doi = "10.1023/A:1022137612328",

language = "English",

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pages = "177--182",

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T1 - Ga-promoted tungstated zirconia catalyst for n-butane isomerization

AU - Chen, Xiao Rong

AU - Chen, Chang Lin

AU - Xu, Nan Ping

AU - Han, Song

AU - Mou, Chung Yuan

N1 - Funding Information: We thank Professor Jianyi Shen from Nanjing University for help in the microcalorimetric study. Financial support from the Educational Department of Jiangsu Province (Project 00KJB530001 to CLC), the Science and Technology Department of Jiangsu Province (Project GB2002017 to CLC), and Key Laboratory of Chemical Engineering and Technology of Jiangsu Province is gratefully acknowledged.

PY - 2003/2

Y1 - 2003/2

N2 - Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N2 adsorption, NH3 temperature-programmed desorption (NH3 TPD), microcalorimetry and H2 temperature-programmed reduction (H2 TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.

AB - Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N2 adsorption, NH3 temperature-programmed desorption (NH3 TPD), microcalorimetry and H2 temperature-programmed reduction (H2 TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.

KW - Gallium

KW - N-butane isomerization

KW - Tungstated zirconia

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Ga-promoted tungstated zirconia catalyst for n-butane isomerization

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