X-Ray crystallographic structure determination of an aziridinone. Demonstration of a non-planar arrangement at nitrogen in an α-lactam

Andrew H.J. Wang; Iain C. Paul; Erach R. Talaty; Aubry E. Dupuy

doi:10.1039/C39720000043

X-Ray crystallographic structure determination of an aziridinone. Demonstration of a non-planar arrangement at nitrogen in an α-lactam

Andrew H.J. Wang, Iain C. Paul, Erach R. Talaty, Aubry E. Dupuy

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The X-ray crystal-structure analysis of 1,3-diadamantylaziridinone (1b) demonstrates that the configuration at nitrogen is pyramidal (N lying 0·534 Å from the plane defined by its three substituents) and that the adamantyl groups are trans to each other.

Original language	English
Pages (from-to)	43-44
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	0
Issue number	2
DOIs	https://doi.org/10.1039/C39720000043
Publication status	Published - 1972
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "X-Ray crystallographic structure determination of an aziridinone. Demonstration of a non-planar arrangement at nitrogen in an α-lactam",

abstract = "The X-ray crystal-structure analysis of 1,3-diadamantylaziridinone (1b) demonstrates that the configuration at nitrogen is pyramidal (N lying 0·534 {\AA} from the plane defined by its three substituents) and that the adamantyl groups are trans to each other.",

author = "Wang, {Andrew H.J.} and Paul, {Iain C.} and Talaty, {Erach R.} and Dupuy, {Aubry E.}",

year = "1972",

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AU - Wang, Andrew H.J.

AU - Paul, Iain C.

AU - Talaty, Erach R.

AU - Dupuy, Aubry E.

PY - 1972

Y1 - 1972

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AB - The X-ray crystal-structure analysis of 1,3-diadamantylaziridinone (1b) demonstrates that the configuration at nitrogen is pyramidal (N lying 0·534 Å from the plane defined by its three substituents) and that the adamantyl groups are trans to each other.

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X-Ray crystallographic structure determination of an aziridinone. Demonstration of a non-planar arrangement at nitrogen in an α-lactam

Abstract

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