The structure of the C16H16·Fe 3(CO)9 complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene

Andrew H.J. Wang; Iain C. Paul; G. N. Schrauzer

doi:10.1039/C39720000736

The structure of the C₁₆H₁₆·Fe ₃(CO)₉ complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene

Andrew H.J. Wang
, Iain C. Paul
, G. N. Schrauzer

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The structure (IV) of the C₁₆H₁₆·Fe ₃(CO)₉ complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene has been shown to contain a vinyl radical to which one of the iron atoms in an Fe₂(CO)₆ group forms a π-bond while the other is σ-bonded; this result corrects an earlier structural assignment.

Original language	English
Pages (from-to)	736-737
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	0
Issue number	12
DOIs	https://doi.org/10.1039/C39720000736
Publication status	Published - 1972
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "The structure of the C16H16·Fe 3(CO)9 complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene",

abstract = "The structure (IV) of the C16H16·Fe 3(CO)9 complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene has been shown to contain a vinyl radical to which one of the iron atoms in an Fe2(CO)6 group forms a π-bond while the other is σ-bonded; this result corrects an earlier structural assignment.",

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AU - Schrauzer, G. N.

PY - 1972

Y1 - 1972

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AB - The structure (IV) of the C16H16·Fe 3(CO)9 complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene has been shown to contain a vinyl radical to which one of the iron atoms in an Fe2(CO)6 group forms a π-bond while the other is σ-bonded; this result corrects an earlier structural assignment.

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The structure of the C₁₆H₁₆·Fe ₃(CO)₉ complex derived from iron tricarbonyl complexes of dimers of cyclo-octatetraene

Abstract

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