Abstract
The metal oxide-incorporated or -grafted mesoporous silica nanoparticles and nanotubes have been prepared efficiently via a two-step synthetic process, which includes a pre-hydrolysis of the TEOS and metal alkoxides or salts in acidic solution (pH < 1.0), and fast co-condensation of silica, metal oxides and surfactant in alkaline ammonia solution (pH 8.0-9.0). Because the presence of the cationic surfactant and a proper pH range could make the silica condensation fast enough to match a relatively quick metal-oxide condensation, various metal oxides (e.g. Al-, Ti-, V-, Zr-, Fe-oxides) can be homogeneously incorporated into the silica framework or grafted on the silica surface. The XRD, reflectance UV-vis and FT-IR spectrometry and solid state NMR have been performed to further identify the successful incorporation and grafting of metal oxides. The metal oxides-incorporated mesoporous silica nanotubes or nanoparticles with high surface area, large mesoporosity and textural porosity can be considered as a capable catalyst of high connectivity and accessibility. The Al-incorporated mesoporous silica nanoparticles show higher catalytic activity toward the cumene-cracking reaction than the typical mesoporous aluminosilicate.
Original language | English |
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Pages (from-to) | 81-87 |
Number of pages | 7 |
Journal | Catalysis Today |
Volume | 97 |
Issue number | 1 SPEC. ISS. |
DOIs | |
Publication status | Published - 2004 |
Externally published | Yes |
Keywords
- MCM-41
- Mesoporous silica nanoparticles
- Tubules-within-tubule
ASJC Scopus subject areas
- Catalysis
- General Chemistry