Synthesis and Characterization of Sol–Gelled Barium Zirconate as Novel MTA Radiopacifiers

Hsiu Na Lin, May Show Chen, Pei Jung Chang, Yao Chi Lee, Chin Yi Chen, Yuh Jing Chiou, Chung Kwei Lin

Research output: Contribution to journalArticlepeer-review

Abstract

Barium zirconate (BaZrO3, BZO), which exhibits superior mechanical, thermal, and chemical stability, has been widely used in many applications. In dentistry, BZO is used as a radiopacifier in mineral trioxide aggregates (MTAs) for endodontic filling applications. In the present study, BZO was prepared using the sol–gel process, followed by calcination at 700–1000 °C. The calcined BZO powders were investigated using X-ray diffraction and scanning electron microscopy. Thereafter, MTA-like cements with the addition of calcined BZO powder were evaluated to determine the optimal composition based on radiopacity, diametral tensile strength (DTS), and setting times. The experimental results showed that calcined BZO exhibited a majority BZO phase with minor zirconia crystals. The crystallinity, the percentage, and the average crystalline size of BZO increased with the increasing calcination temperature. The optimal MTA-like cement was obtained by adding 20% of the 700 °C-calcined BZO powder. The initial and final setting times were 25 and 32 min, respectively. They were significantly shorter than those (70 and 56 min, respectively) prepared with commercial BZO powder. It exhibited a radiopacity of 3.60 ± 0.22 mmAl and a DTS of 3.02 ± 0.18 MPa. After 28 days of simulated oral environment storage, the radiopacity and DTS decreased to 3.36 ± 0.53 mmAl and 2.84 ± 0.27 MPa, respectively. This suggests that 700 °C-calcined BZO powder has potential as a novel radiopacifier for MTAs.

Original languageEnglish
Article number3015
JournalMaterials
Volume17
Issue number12
DOIs
Publication statusPublished - Jun 2024

Keywords

  • barium zirconate
  • calcination
  • diametral tensile strength
  • mineral trioxide aggregates
  • radiopacity
  • setting time
  • sol–gel

ASJC Scopus subject areas

  • General Materials Science
  • Condensed Matter Physics

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