Strongly acidic mesoporous aluminosilicates prepared from zeolite seeds: Acylation of anisole with octanyl chloride

Pei Chun Shih; Jung Hui Wang; Chung Yuan Mou

doi:10.1016/j.cattod.2004.06.025

Strongly acidic mesoporous aluminosilicates prepared from zeolite seeds: Acylation of anisole with octanyl chloride

Pei Chun Shih, Jung Hui Wang, Chung Yuan Mou

Research output: Contribution to journal › Conference article › peer-review

35 Citations (Scopus)

Abstract

Ultrastable acidic mesoporous aluminosilicates (MCM-48-S, MCM-48-SH, MCM-41-S) with mesostructures, strong acidity, and high hydrothermal stability was synthesized from assembly of cetyltriammonium bromide (CTAB) and pre-formed zeolite Beta seed. The catalytic application of the solid acid catalysts (HMCM-41-S and HMCM-48-SH) was demonstrated with the Friedel-Crafts acylation of aromatics. High conversion (>90%) and high selectivity (100%) were obtained.

Original language	English
Pages (from-to)	365-370
Number of pages	6
Journal	Catalysis Today
Volume	93-95
DOIs	https://doi.org/10.1016/j.cattod.2004.06.025
Publication status	Published - Sept 1 2004
Externally published	Yes
Event	Selections from the Presentations of the 3rd Asia-Pacific Congress - Dalian, China Duration: Oct 12 2003 → Oct 12 2003

Keywords

Acylation
Anisole
Mesoporous aluminosilicates
Zeolite seed

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1016/j.cattod.2004.06.025

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title = "Strongly acidic mesoporous aluminosilicates prepared from zeolite seeds: Acylation of anisole with octanyl chloride",

abstract = "Ultrastable acidic mesoporous aluminosilicates (MCM-48-S, MCM-48-SH, MCM-41-S) with mesostructures, strong acidity, and high hydrothermal stability was synthesized from assembly of cetyltriammonium bromide (CTAB) and pre-formed zeolite Beta seed. The catalytic application of the solid acid catalysts (HMCM-41-S and HMCM-48-SH) was demonstrated with the Friedel-Crafts acylation of aromatics. High conversion (>90%) and high selectivity (100%) were obtained.",

keywords = "Acylation, Anisole, Mesoporous aluminosilicates, Zeolite seed",

author = "Shih, {Pei Chun} and Wang, {Jung Hui} and Mou, {Chung Yuan}",

note = "Funding Information: This work was supported by a grant from the Ministry of Education through Academy Excellent program.; Selections from the Presentations of the 3rd Asia-Pacific Congress ; Conference date: 12-10-2003 Through 12-10-2003",

year = "2004",

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doi = "10.1016/j.cattod.2004.06.025",

language = "English",

volume = "93-95",

pages = "365--370",

journal = "Catalysis Today",

issn = "0920-5861",

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TY - JOUR

T1 - Strongly acidic mesoporous aluminosilicates prepared from zeolite seeds

T2 - Selections from the Presentations of the 3rd Asia-Pacific Congress

AU - Shih, Pei Chun

AU - Wang, Jung Hui

AU - Mou, Chung Yuan

N1 - Funding Information: This work was supported by a grant from the Ministry of Education through Academy Excellent program.

PY - 2004/9/1

Y1 - 2004/9/1

N2 - Ultrastable acidic mesoporous aluminosilicates (MCM-48-S, MCM-48-SH, MCM-41-S) with mesostructures, strong acidity, and high hydrothermal stability was synthesized from assembly of cetyltriammonium bromide (CTAB) and pre-formed zeolite Beta seed. The catalytic application of the solid acid catalysts (HMCM-41-S and HMCM-48-SH) was demonstrated with the Friedel-Crafts acylation of aromatics. High conversion (>90%) and high selectivity (100%) were obtained.

AB - Ultrastable acidic mesoporous aluminosilicates (MCM-48-S, MCM-48-SH, MCM-41-S) with mesostructures, strong acidity, and high hydrothermal stability was synthesized from assembly of cetyltriammonium bromide (CTAB) and pre-formed zeolite Beta seed. The catalytic application of the solid acid catalysts (HMCM-41-S and HMCM-48-SH) was demonstrated with the Friedel-Crafts acylation of aromatics. High conversion (>90%) and high selectivity (100%) were obtained.

KW - Acylation

KW - Anisole

KW - Mesoporous aluminosilicates

KW - Zeolite seed

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DO - 10.1016/j.cattod.2004.06.025

M3 - Conference article

AN - SCOPUS:4344588000

SN - 0920-5861

VL - 93-95

SP - 365

EP - 370

JO - Catalysis Today

JF - Catalysis Today

Y2 - 12 October 2003 through 12 October 2003

ER -

Strongly acidic mesoporous aluminosilicates prepared from zeolite seeds: Acylation of anisole with octanyl chloride

Abstract

Keywords

ASJC Scopus subject areas

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