Sodium trimethylsilanethiolate in novel cyclizations for synthesis of aromatic heterotricyclic compounds

Long Li Lai; Pen Yuan Lin; Wen Hong Huang; Min Jen Shiao; Jih Ru Hwu

doi:10.1016/S0040-4039(00)73233-3

Sodium trimethylsilanethiolate in novel cyclizations for synthesis of aromatic heterotricyclic compounds

Long Li Lai, Pen Yuan Lin, Wen Hong Huang, Min Jen Shiao, Jih Ru Hwu

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A new method was developed for synthesis of aromatic heterotricyclic compounds in 50-64% yields from diaryls bearing a functionality including OMe, COOMe, and CN, and a leaving group (i.e., F and OMe) by use of Me₃SiSNa in 1,3-dimethyl-2-imidazolidinone at 120-150 °C.

Original language	English
Pages (from-to)	3545-3546
Number of pages	2
Journal	Tetrahedron Letters
Volume	35
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4039(00)73233-3
Publication status	Published - May 23 1994
Externally published	Yes

ASJC Scopus subject areas

Drug Discovery
Biochemistry
Organic Chemistry

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abstract = "A new method was developed for synthesis of aromatic heterotricyclic compounds in 50-64% yields from diaryls bearing a functionality including OMe, COOMe, and CN, and a leaving group (i.e., F and OMe) by use of Me3SiSNa in 1,3-dimethyl-2-imidazolidinone at 120-150 °C.",

author = "Lai, {Long Li} and Lin, {Pen Yuan} and Huang, {Wen Hong} and Shiao, {Min Jen} and {Ru Hwu}, Jih",

year = "1994",

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T1 - Sodium trimethylsilanethiolate in novel cyclizations for synthesis of aromatic heterotricyclic compounds

AU - Lai, Long Li

AU - Lin, Pen Yuan

AU - Huang, Wen Hong

AU - Shiao, Min Jen

AU - Ru Hwu, Jih

PY - 1994/5/23

Y1 - 1994/5/23

N2 - A new method was developed for synthesis of aromatic heterotricyclic compounds in 50-64% yields from diaryls bearing a functionality including OMe, COOMe, and CN, and a leaving group (i.e., F and OMe) by use of Me3SiSNa in 1,3-dimethyl-2-imidazolidinone at 120-150 °C.

AB - A new method was developed for synthesis of aromatic heterotricyclic compounds in 50-64% yields from diaryls bearing a functionality including OMe, COOMe, and CN, and a leaving group (i.e., F and OMe) by use of Me3SiSNa in 1,3-dimethyl-2-imidazolidinone at 120-150 °C.

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DO - 10.1016/S0040-4039(00)73233-3

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JO - Tetrahedron Letters

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ER -

Sodium trimethylsilanethiolate in novel cyclizations for synthesis of aromatic heterotricyclic compounds

Abstract

ASJC Scopus subject areas

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