Pulsed laser deposition of (MoO3)1 - X(V 2O5)x thin films: Preparation, characterization and gasochromic studies

Chung Chieh Chang; Jiu Yong Luo; Ta Kun Chen; Kuo Wei Yeh; Tzu Wen Huang; Chia Hao Hsu; Wei Hsiang Chao; Chung Ting Ke; Po Chun Hsu; Ming Jye Wang; Mau Kuen Wu

doi:10.1016/j.tsf.2010.09.003

Pulsed laser deposition of (MoO₃)_{1 - X}(V ₂O₅)_x thin films: Preparation, characterization and gasochromic studies

Chung Chieh Chang, Jiu Yong Luo, Ta Kun Chen, Kuo Wei Yeh, Tzu Wen Huang, Chia Hao Hsu, Wei Hsiang Chao, Chung Ting Ke, Po Chun Hsu, Ming Jye Wang, Mau Kuen Wu

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

In this study we demonstrate a new composite oxide thin films of (MoO ₃)_{1 - x}(V₂O₅)_x, x = 0, 0.01, 0.03, and 0.05, fabricated by pulsed laser deposition (PLD). The performance of platinum (Pt) catalyst activated hydrogen gas sensor with modified (MoO₃)_{1 - x}(V₂O₅) _x thin films were investigated. The thickness of the (MoO ₃)_{1 - x}(V₂O₅)_x thin film is about 600-650 nm and its surface has a uniform morphology. Our results show that the gasochromic sensors prepared by (MoO₃)_0.99(V ₂O₅)_0.01 thin film exhibited excellent hydrogen sensibility. The response and recovery time are in the range of 9-15 min for coloration and bleaching at room temperature under H₂ atmosphere. The results also show that (MoO₃)_{1 - x}(V₂O ₅)_x/Pt (x = 0.01, 0.03, 0.05) thin films perform better gasochromic capability than the pristine MoO₃/Pt sample.

Original language	English
Pages (from-to)	1552-1557
Number of pages	6
Journal	Thin Solid Films
Volume	519
Issue number	5
DOIs	https://doi.org/10.1016/j.tsf.2010.09.003
Publication status	Published - Dec 30 2010
Externally published	Yes

Keywords

Hydrogen sensor
Molybdenum oxide
PLD
Vanadium oxide gasochromic

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Surfaces and Interfaces

Access to Document

10.1016/j.tsf.2010.09.003

Cite this

@article{e939077be10446f391c904939b4dbbd6,

title = "Pulsed laser deposition of (MoO3)1 - X(V 2O5)x thin films: Preparation, characterization and gasochromic studies",

abstract = "In this study we demonstrate a new composite oxide thin films of (MoO 3)1 - x(V2O5)x, x = 0, 0.01, 0.03, and 0.05, fabricated by pulsed laser deposition (PLD). The performance of platinum (Pt) catalyst activated hydrogen gas sensor with modified (MoO3)1 - x(V2O5) x thin films were investigated. The thickness of the (MoO 3)1 - x(V2O5)x thin film is about 600-650 nm and its surface has a uniform morphology. Our results show that the gasochromic sensors prepared by (MoO3)0.99(V 2O5)0.01 thin film exhibited excellent hydrogen sensibility. The response and recovery time are in the range of 9-15 min for coloration and bleaching at room temperature under H2 atmosphere. The results also show that (MoO3)1 - x(V2O 5)x/Pt (x = 0.01, 0.03, 0.05) thin films perform better gasochromic capability than the pristine MoO3/Pt sample.",

keywords = "Hydrogen sensor, Molybdenum oxide, PLD, Vanadium oxide gasochromic",

author = "Chang, \{Chung Chieh\} and Luo, \{Jiu Yong\} and Chen, \{Ta Kun\} and Yeh, \{Kuo Wei\} and Huang, \{Tzu Wen\} and Hsu, \{Chia Hao\} and Chao, \{Wei Hsiang\} and Ke, \{Chung Ting\} and Hsu, \{Po Chun\} and Wang, \{Ming Jye\} and Wu, \{Mau Kuen\}",

note = "Funding Information: This work was founded by National Science Council of Taiwan under Grant NSC-96-2112-M-001-026-MY3 and NSC-98-2119-M-001-025 .",

year = "2010",

month = dec,

day = "30",

doi = "10.1016/j.tsf.2010.09.003",

language = "English",

volume = "519",

pages = "1552--1557",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier B.V.",

number = "5",

}

TY - JOUR

T1 - Pulsed laser deposition of (MoO3)1 - X(V 2O5)x thin films

T2 - Preparation, characterization and gasochromic studies

AU - Chang, Chung Chieh

AU - Luo, Jiu Yong

AU - Chen, Ta Kun

AU - Yeh, Kuo Wei

AU - Huang, Tzu Wen

AU - Hsu, Chia Hao

AU - Chao, Wei Hsiang

AU - Ke, Chung Ting

AU - Hsu, Po Chun

AU - Wang, Ming Jye

AU - Wu, Mau Kuen

N1 - Funding Information: This work was founded by National Science Council of Taiwan under Grant NSC-96-2112-M-001-026-MY3 and NSC-98-2119-M-001-025 .

PY - 2010/12/30

Y1 - 2010/12/30

N2 - In this study we demonstrate a new composite oxide thin films of (MoO 3)1 - x(V2O5)x, x = 0, 0.01, 0.03, and 0.05, fabricated by pulsed laser deposition (PLD). The performance of platinum (Pt) catalyst activated hydrogen gas sensor with modified (MoO3)1 - x(V2O5) x thin films were investigated. The thickness of the (MoO 3)1 - x(V2O5)x thin film is about 600-650 nm and its surface has a uniform morphology. Our results show that the gasochromic sensors prepared by (MoO3)0.99(V 2O5)0.01 thin film exhibited excellent hydrogen sensibility. The response and recovery time are in the range of 9-15 min for coloration and bleaching at room temperature under H2 atmosphere. The results also show that (MoO3)1 - x(V2O 5)x/Pt (x = 0.01, 0.03, 0.05) thin films perform better gasochromic capability than the pristine MoO3/Pt sample.

AB - In this study we demonstrate a new composite oxide thin films of (MoO 3)1 - x(V2O5)x, x = 0, 0.01, 0.03, and 0.05, fabricated by pulsed laser deposition (PLD). The performance of platinum (Pt) catalyst activated hydrogen gas sensor with modified (MoO3)1 - x(V2O5) x thin films were investigated. The thickness of the (MoO 3)1 - x(V2O5)x thin film is about 600-650 nm and its surface has a uniform morphology. Our results show that the gasochromic sensors prepared by (MoO3)0.99(V 2O5)0.01 thin film exhibited excellent hydrogen sensibility. The response and recovery time are in the range of 9-15 min for coloration and bleaching at room temperature under H2 atmosphere. The results also show that (MoO3)1 - x(V2O 5)x/Pt (x = 0.01, 0.03, 0.05) thin films perform better gasochromic capability than the pristine MoO3/Pt sample.

KW - Hydrogen sensor

KW - Molybdenum oxide

KW - PLD

KW - Vanadium oxide gasochromic

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