Preparation of a novel Pd/layered double hydroxide composite membrane for hydrogen filtration and characterization by thermal cycling

Yen Hsun Chi; Jun Yen Uan; Meng Chang Lin; Yu Li Lin; Jin Hua Huang

doi:10.1016/j.ijhydene.2013.08.052

Preparation of a novel Pd/layered double hydroxide composite membrane for hydrogen filtration and characterization by thermal cycling

Yen Hsun Chi, Jun Yen Uan, Meng Chang Lin, Yu Li Lin, Jin Hua Huang

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A layered double hydroxide (LDH) layer was grown directly on a porous stainless steel (PSS) surface to reduce the pore opening of the PSS and to be a middle layer retarding Pd/Fe interdiffusion. A thin Pd film (∼7.85 μm) was plated on the modified PSS tube by an electroless plating method. A helium leak test proved that the thin Pd on the LDH-modified PSS substrate was free of defects. The membrane had a H₂ flux of 28-36 m³/(m ² h) and H₂/He selectivity larger than 2000 at a pressure difference of 1 bar. Thermal cycling between room temperature and 673 K was performed and showed that the membrane exhibited good permeance and selectivity. Long-term evaluation (1500 h) of the membrane at 673 K showed static results of H₂ flux (∼30 m³/(m² h)) and H ₂/He selectivity (∼2000) over the 1500 h test period.

Original language	English
Pages (from-to)	13734-13741
Number of pages	8
Journal	International Journal of Hydrogen Energy
Volume	38
Issue number	31
DOIs	https://doi.org/10.1016/j.ijhydene.2013.08.052
Publication status	Published - Oct 17 2013
Externally published	Yes

Keywords

Electroless plating
Hydrogen
Layered double hydroxide
Pd membrane
Porous stainless steel

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ijhydene.2013.08.052

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title = "Preparation of a novel Pd/layered double hydroxide composite membrane for hydrogen filtration and characterization by thermal cycling",

abstract = "A layered double hydroxide (LDH) layer was grown directly on a porous stainless steel (PSS) surface to reduce the pore opening of the PSS and to be a middle layer retarding Pd/Fe interdiffusion. A thin Pd film (∼7.85 μm) was plated on the modified PSS tube by an electroless plating method. A helium leak test proved that the thin Pd on the LDH-modified PSS substrate was free of defects. The membrane had a H2 flux of 28-36 m3/(m 2 h) and H2/He selectivity larger than 2000 at a pressure difference of 1 bar. Thermal cycling between room temperature and 673 K was performed and showed that the membrane exhibited good permeance and selectivity. Long-term evaluation (1500 h) of the membrane at 673 K showed static results of H2 flux (∼30 m3/(m2 h)) and H 2/He selectivity (∼2000) over the 1500 h test period.",

keywords = "Electroless plating, Hydrogen, Layered double hydroxide, Pd membrane, Porous stainless steel",

author = "Chi, {Yen Hsun} and Uan, {Jun Yen} and Lin, {Meng Chang} and Lin, {Yu Li} and Huang, {Jin Hua}",

note = "Funding Information: Financial support from the Bureau of Energy (No. 102-D0108 ), Ministry of Economic Affairs of Taiwan , is gratefully acknowledged.",

year = "2013",

month = oct,

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doi = "10.1016/j.ijhydene.2013.08.052",

language = "English",

volume = "38",

pages = "13734--13741",

journal = "International Journal of Hydrogen Energy",

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T1 - Preparation of a novel Pd/layered double hydroxide composite membrane for hydrogen filtration and characterization by thermal cycling

AU - Chi, Yen Hsun

AU - Uan, Jun Yen

AU - Lin, Meng Chang

AU - Lin, Yu Li

AU - Huang, Jin Hua

N1 - Funding Information: Financial support from the Bureau of Energy (No. 102-D0108 ), Ministry of Economic Affairs of Taiwan , is gratefully acknowledged.

PY - 2013/10/17

Y1 - 2013/10/17

N2 - A layered double hydroxide (LDH) layer was grown directly on a porous stainless steel (PSS) surface to reduce the pore opening of the PSS and to be a middle layer retarding Pd/Fe interdiffusion. A thin Pd film (∼7.85 μm) was plated on the modified PSS tube by an electroless plating method. A helium leak test proved that the thin Pd on the LDH-modified PSS substrate was free of defects. The membrane had a H2 flux of 28-36 m3/(m 2 h) and H2/He selectivity larger than 2000 at a pressure difference of 1 bar. Thermal cycling between room temperature and 673 K was performed and showed that the membrane exhibited good permeance and selectivity. Long-term evaluation (1500 h) of the membrane at 673 K showed static results of H2 flux (∼30 m3/(m2 h)) and H 2/He selectivity (∼2000) over the 1500 h test period.

AB - A layered double hydroxide (LDH) layer was grown directly on a porous stainless steel (PSS) surface to reduce the pore opening of the PSS and to be a middle layer retarding Pd/Fe interdiffusion. A thin Pd film (∼7.85 μm) was plated on the modified PSS tube by an electroless plating method. A helium leak test proved that the thin Pd on the LDH-modified PSS substrate was free of defects. The membrane had a H2 flux of 28-36 m3/(m 2 h) and H2/He selectivity larger than 2000 at a pressure difference of 1 bar. Thermal cycling between room temperature and 673 K was performed and showed that the membrane exhibited good permeance and selectivity. Long-term evaluation (1500 h) of the membrane at 673 K showed static results of H2 flux (∼30 m3/(m2 h)) and H 2/He selectivity (∼2000) over the 1500 h test period.

KW - Electroless plating

KW - Hydrogen

KW - Layered double hydroxide

KW - Pd membrane

KW - Porous stainless steel

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M3 - Article

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SN - 0360-3199

VL - 38

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EP - 13741

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 31

ER -

Preparation of a novel Pd/layered double hydroxide composite membrane for hydrogen filtration and characterization by thermal cycling

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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