TY - JOUR
T1 - Photoreaction of neutral 9-aminoacridine in glycerol:Water glass characterized by satellite holes and antiholes
AU - Chiang, Chien Chih
AU - Mou, Chung Yuan
AU - Chang, Ta Chau
N1 - Funding Information:
This work was supported by the Academia Sinica and the NSC of the Republic of China (Grant No. NSC-86-2113-M001-045).
PY - 1997/7/18
Y1 - 1997/7/18
N2 - Satellite holes and antiholes in the hole burned (HB) spectrum are used to determine the photoproduct of 9-aminoacridine (9AA) doped in glycerol:water (Gl:H2O) glass with pH = 13. Although monoprotonated 9AA is the photoproduct of the imino form of neutral 9AA, antihole recovery implies that the excited state 9AA returns to original form of 9AA predominantly. Furthermore, similar satellite holes but different antihole structures are observed in the HB spectrum of 9AA doped in polyvinyl butyral film, implying that different HB mechanisms are involved.
AB - Satellite holes and antiholes in the hole burned (HB) spectrum are used to determine the photoproduct of 9-aminoacridine (9AA) doped in glycerol:water (Gl:H2O) glass with pH = 13. Although monoprotonated 9AA is the photoproduct of the imino form of neutral 9AA, antihole recovery implies that the excited state 9AA returns to original form of 9AA predominantly. Furthermore, similar satellite holes but different antihole structures are observed in the HB spectrum of 9AA doped in polyvinyl butyral film, implying that different HB mechanisms are involved.
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U2 - 10.1016/S0009-2614(97)00567-8
DO - 10.1016/S0009-2614(97)00567-8
M3 - Article
AN - SCOPUS:0031577247
SN - 0009-2614
VL - 273
SP - 153
EP - 158
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3-4
ER -