Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method

F. D. Mai; C. C. Chen; J. L. Chen; S. C. Liu

doi:10.1016/j.chroma.2008.01.027

Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method

F. D. Mai, C. C. Chen, J. L. Chen, S. C. Liu

Department of Biochemistry and Molecular Cell Biology

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

Heterogeneous photocatalytic treatment of a dye called methyl green (MG), which was simulating textile wastewater from associated auxiliary chemicals, was investigated using ZnO. A detailed investigation of the photodegradation of MG has been carried out in the ZnO suspension irradiated with visible light. The effects of various factors - viz. pH values, amount of catalyst, initial dye concentration, and the presence of NaCl, Na₂CO₃, H₂O₂, and Na₂S₂O₈ - on the degradation efficiency were studied. Thirty-two intermediates were separated, identified, and characterized by high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry (HPLC-ESI-DAD-MS) technology, giving us insight into the pathways of the degradation process.

Original language	English
Pages (from-to)	355-365
Number of pages	11
Journal	Journal of Chromatography A
Volume	1189
Issue number	1-2
DOIs	https://doi.org/10.1016/j.chroma.2008.01.027
Publication status	Published - May 2 2008

Keywords

HPLC-ESI-DAD-MS
Methyl green
Photodegradation
ZnO

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Organic Chemistry

Access to Document

10.1016/j.chroma.2008.01.027

Fingerprint

Dive into the research topics of 'Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method'. Together they form a unique fingerprint.

Cite this

Mai, F. D., Chen, C. C., Chen, J. L., & Liu, S. C. (2008). Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method. Journal of Chromatography A, 1189(1-2), 355-365. https://doi.org/10.1016/j.chroma.2008.01.027

Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method. / Mai, F. D.; Chen, C. C.; Chen, J. L. et al.
In: Journal of Chromatography A, Vol. 1189, No. 1-2, 02.05.2008, p. 355-365.

Research output: Contribution to journal › Article › peer-review

Mai, FD, Chen, CC, Chen, JL & Liu, SC 2008, 'Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method', Journal of Chromatography A, vol. 1189, no. 1-2, pp. 355-365. https://doi.org/10.1016/j.chroma.2008.01.027

Mai FD, Chen CC, Chen JL, Liu SC. Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method. Journal of Chromatography A. 2008 May 2;1189(1-2):355-365. doi: 10.1016/j.chroma.2008.01.027

Mai, F. D. ; Chen, C. C. ; Chen, J. L. et al. / Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method. In: Journal of Chromatography A. 2008 ; Vol. 1189, No. 1-2. pp. 355-365.

@article{c4024790c45b45b7ac778efdcc65868f,

title = "Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method",

abstract = "Heterogeneous photocatalytic treatment of a dye called methyl green (MG), which was simulating textile wastewater from associated auxiliary chemicals, was investigated using ZnO. A detailed investigation of the photodegradation of MG has been carried out in the ZnO suspension irradiated with visible light. The effects of various factors - viz. pH values, amount of catalyst, initial dye concentration, and the presence of NaCl, Na2CO3, H2O2, and Na2S2O8 - on the degradation efficiency were studied. Thirty-two intermediates were separated, identified, and characterized by high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry (HPLC-ESI-DAD-MS) technology, giving us insight into the pathways of the degradation process.",

keywords = "HPLC-ESI-DAD-MS, Methyl green, Photodegradation, ZnO",

author = "Mai, {F. D.} and Chen, {C. C.} and Chen, {J. L.} and Liu, {S. C.}",

year = "2008",

month = may,

day = "2",

doi = "10.1016/j.chroma.2008.01.027",

language = "English",

volume = "1189",

pages = "355--365",

journal = "Journal of Chromatography A",

issn = "0021-9673",

number = "1-2",

}

TY - JOUR

T1 - Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method

AU - Mai, F. D.

AU - Chen, C. C.

AU - Chen, J. L.

AU - Liu, S. C.

PY - 2008/5/2

Y1 - 2008/5/2

N2 - Heterogeneous photocatalytic treatment of a dye called methyl green (MG), which was simulating textile wastewater from associated auxiliary chemicals, was investigated using ZnO. A detailed investigation of the photodegradation of MG has been carried out in the ZnO suspension irradiated with visible light. The effects of various factors - viz. pH values, amount of catalyst, initial dye concentration, and the presence of NaCl, Na2CO3, H2O2, and Na2S2O8 - on the degradation efficiency were studied. Thirty-two intermediates were separated, identified, and characterized by high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry (HPLC-ESI-DAD-MS) technology, giving us insight into the pathways of the degradation process.

AB - Heterogeneous photocatalytic treatment of a dye called methyl green (MG), which was simulating textile wastewater from associated auxiliary chemicals, was investigated using ZnO. A detailed investigation of the photodegradation of MG has been carried out in the ZnO suspension irradiated with visible light. The effects of various factors - viz. pH values, amount of catalyst, initial dye concentration, and the presence of NaCl, Na2CO3, H2O2, and Na2S2O8 - on the degradation efficiency were studied. Thirty-two intermediates were separated, identified, and characterized by high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry (HPLC-ESI-DAD-MS) technology, giving us insight into the pathways of the degradation process.

KW - HPLC-ESI-DAD-MS

KW - Methyl green

KW - Photodegradation

KW - ZnO

UR - http://www.scopus.com/inward/record.url?scp=41949142885&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=41949142885&partnerID=8YFLogxK

U2 - 10.1016/j.chroma.2008.01.027

DO - 10.1016/j.chroma.2008.01.027

M3 - Article

C2 - 18242624

AN - SCOPUS:41949142885

SN - 0021-9673

VL - 1189

SP - 355

EP - 365

JO - Journal of Chromatography A

JF - Journal of Chromatography A

IS - 1-2

ER -

Photodegradation of methyl green using visible irradiation in ZnO suspensions. Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this