Personal Exposure to Sulfuric Acid in the Electroplating Industry: Development and Validation of a Predictive Model

Austin B. Wang, Kai Jen Chuang, Ven Shing Wang, Ta Yuan Chang

Research output: Contribution to journalArticlepeer-review

Abstract

This study aimed to measure personal exposure to sulfuric acid in the electroplating industry to establish a predictive model and test its validation. We collected indoor air parameters and related information from four electroplating plants. Silica gel sorbents were used to collect air samples using high-performance ion chromatography. We collected air samples from three plants (i.e., Plant B, Plant C, and Plant D) and applied multiple linear regressions to build a predictive model. Eight samples collected from the fourth plant (i.e., Plant A) were used to validate the model. A total of 41 samples were collected with a mean of 25.0 ± 9.8 μg/m3 (range 12.1–51.7 μg/m3) in this study, including Plant A (8 samples, 17.5 ± 2.8 μg/m3, 13.0–22.0 μg/m3), Plant B (11 samples, 36.5 ± 9.7 μg/m3, 23.1–51.7 μg/m3), Plant C (11 samples, 16.4 ± 1.7 μg/m3, 12.1–17.8 μg/m3), and Plant D (11 samples, 27.4 ± 1.7 μg/m3, 24.1–29.9 μg/m3). Plant B was significantly higher in sulfuric acid than the other plants. Workers from the electroplating process plants were exposed to sulfuric acid at 29.0 ± 11.5 μg/m3. The predictive model for personal exposure to sulfuric acid fit the data well (r2 = 0.853; adjusted r2 = 0.837) and had an accuracy of 5.52 μg/m3 (bias ± precision; 4.98 ± 2.38 μg/m3), validated by the personal sampling of the fourth plant. This study observed that sulfuric acid exposure was lower than the permissible exposure level of 1000 μg/m3 in Taiwan and the United States, and only two samples were lower than the European Union standard of 50 μg/m3. The developed model can be applied in epidemiological studies to predict personal exposure to sulfuric acid in plants using electroplating.

Original languageEnglish
Article number489
JournalToxics
Volume12
Issue number7
DOIs
Publication statusPublished - Jul 2024

Keywords

  • electroplating
  • exposure assessment
  • personal exposure
  • predictive model
  • sulfuric acid

ASJC Scopus subject areas

  • Toxicology
  • Health, Toxicology and Mutagenesis
  • Chemical Health and Safety

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