Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C60 adduct

Lung Lin Shiu; Tsung I. Lin; Shie Ming Peng; Guor Rong Her; Dar Der Ju; Syh Kun Lin; Jyun Hwei Hwang; Chung Yuan Mou; Tien Yau Luh

doi:10.1039/C39940000647

Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C₆₀ adduct

Lung Lin Shiu
, Tsung I. Lin
, Shie Ming Peng
, Guor Rong Her
, Dar Der Ju
, Syh Kun Lin
, Jyun Hwei Hwang
, Chung Yuan Mou
, Tien Yau Luh

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The first synthesis of the parent TMM-C₆₀ adduct 1 was achieved by means of Pd°-mediated [3 + 2] cycloaddition and its structure was unambiguously proved by spectroscopic means (¹H and ¹³C NMR and MS); a pentane solution of the adduct 1 exhibited a fluorescence emission spectrum with λ_max 704 nm and vibronic fine structure at ambient temperature.

Original language	English
Pages (from-to)	647-648
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39940000647
Publication status	Published - 1994
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39940000647

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Shiu, L. L., Lin, T. I., Peng, S. M., Her, G. R., Ju, D. D., Lin, S. K., Hwang, J. H., Mou, C. Y., & Luh, T. Y. (1994). Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C₆₀ adduct. Journal of the Chemical Society, Chemical Communications, (5), 647-648. https://doi.org/10.1039/C39940000647

Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C₆₀ adduct. / Shiu, Lung Lin; Lin, Tsung I.; Peng, Shie Ming et al.
In: Journal of the Chemical Society, Chemical Communications, No. 5, 1994, p. 647-648.

Research output: Contribution to journal › Article › peer-review

Shiu, LL, Lin, TI, Peng, SM, Her, GR, Ju, DD, Lin, SK, Hwang, JH, Mou, CY & Luh, TY 1994, 'Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C₆₀ adduct', Journal of the Chemical Society, Chemical Communications, no. 5, pp. 647-648. https://doi.org/10.1039/C39940000647

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abstract = "The first synthesis of the parent TMM-C60 adduct 1 was achieved by means of Pd°-mediated [3 + 2] cycloaddition and its structure was unambiguously proved by spectroscopic means (1H and 13C NMR and MS); a pentane solution of the adduct 1 exhibited a fluorescence emission spectrum with λmax 704 nm and vibronic fine structure at ambient temperature.",

author = "Shiu, \{Lung Lin\} and Lin, \{Tsung I.\} and Peng, \{Shie Ming\} and Her, \{Guor Rong\} and Ju, \{Dar Der\} and Lin, \{Syh Kun\} and Hwang, \{Jyun Hwei\} and Mou, \{Chung Yuan\} and Luh, \{Tien Yau\}",

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AU - Shiu, Lung Lin

AU - Lin, Tsung I.

AU - Peng, Shie Ming

AU - Her, Guor Rong

AU - Ju, Dar Der

AU - Lin, Syh Kun

AU - Hwang, Jyun Hwei

AU - Mou, Chung Yuan

AU - Luh, Tien Yau

PY - 1994

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AB - The first synthesis of the parent TMM-C60 adduct 1 was achieved by means of Pd°-mediated [3 + 2] cycloaddition and its structure was unambiguously proved by spectroscopic means (1H and 13C NMR and MS); a pentane solution of the adduct 1 exhibited a fluorescence emission spectrum with λmax 704 nm and vibronic fine structure at ambient temperature.

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Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C₆₀ adduct

Abstract

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