Oxidation of fullerenes by ozone

Jin Pei Deng; Chung Yuan Mou; Chau Chung Han

doi:10.1080/15363839708013323

Oxidation of fullerenes by ozone

Jin Pei Deng, Chung Yuan Mou, Chau Chung Han

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Like typical alkenes, fullerenes can be oxidized by ozone. Epoxidation reaction takes place on C₆₀, and C₆₀On (n=1-5) are formed. Mass spectrometry and chromatocraphy identified the stable existence of two isomers for the dioxides and three for the trioxides in the product mixtures. At lower temperatures, fragmentation occurs and results in the formation of the polar products. C₇₀ and carbon nanotubes also react with ozone but at a much slower rate.

Original language	English
Pages (from-to)	1325-1336
Number of pages	12
Journal	Fullerene Science and Technology
Volume	5
Issue number	7
DOIs	https://doi.org/10.1080/15363839708013323
Publication status	Published - 1997
Externally published	Yes

ASJC Scopus subject areas

General Chemical Engineering

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title = "Oxidation of fullerenes by ozone",

abstract = "Like typical alkenes, fullerenes can be oxidized by ozone. Epoxidation reaction takes place on C60, and C60On (n=1-5) are formed. Mass spectrometry and chromatocraphy identified the stable existence of two isomers for the dioxides and three for the trioxides in the product mixtures. At lower temperatures, fragmentation occurs and results in the formation of the polar products. C70 and carbon nanotubes also react with ozone but at a much slower rate.",

author = "Deng, {Jin Pei} and Mou, {Chung Yuan} and Han, {Chau Chung}",

note = "Funding Information: Generous funding support from the National Science Council of the Republic of",

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AU - Mou, Chung Yuan

AU - Han, Chau Chung

N1 - Funding Information: Generous funding support from the National Science Council of the Republic of

PY - 1997

Y1 - 1997

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AB - Like typical alkenes, fullerenes can be oxidized by ozone. Epoxidation reaction takes place on C60, and C60On (n=1-5) are formed. Mass spectrometry and chromatocraphy identified the stable existence of two isomers for the dioxides and three for the trioxides in the product mixtures. At lower temperatures, fragmentation occurs and results in the formation of the polar products. C70 and carbon nanotubes also react with ozone but at a much slower rate.

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Oxidation of fullerenes by ozone

Abstract

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