On the confinement effect during catalytic reaction over Al-MCM-41

Wen Hua Chen; Shing Jong Huang; Qi Zhao; Hong Ping Lin; Chung Yuan Mou; Shang Bin Liu

doi:10.1007/s11244-008-9139-3

On the confinement effect during catalytic reaction over Al-MCM-41

Wen Hua Chen, Shing Jong Huang, Qi Zhao, Hong Ping Lin, Chung Yuan Mou, Shang Bin Liu

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A comprehensive study has been made on the cracking abilities of mesoporous aluminosillicate MCM-41 materials with different Si/Al ratios (15-∞) and pore diameters (1.6-3.0 nm) by using 1,3,5-triisopropylbenzene (1,3,5-TiPB) cracking as the test reaction. The roles of Al ontent and pore diameter on the catalytic features of the samples were evaluated by the conversion of 1,3,5-TiPB, coke content and deactivation parameters. It is found that the catalytic activity is mainly controlled by adsorptive properties towards the reactant and the dispersion of acid sites. In terms of their catalytic performances, cracking reaction over aluminosilicate mesoporous materials is more favorable for catalysts with smaller pore size and higher Al concentration. Moreover, coking is found responsible for atalyst deactivation during 1,3,5-TiPB cracking reaction over Al-MCM-41.

Original language	English
Pages (from-to)	2-11
Number of pages	10
Journal	Topics in Catalysis
Volume	52
Issue number	1-2
DOIs	https://doi.org/10.1007/s11244-008-9139-3
Publication status	Published - Mar 2009
Externally published	Yes

Keywords

Coking
Confinement effect
Cracking
Mesoporous Al-MCM-41
Pore size
Si/Al ratio

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1007/s11244-008-9139-3

Cite this

@article{67e9bd4b4e5243d7a8d0f95ec56747e8,

title = "On the confinement effect during catalytic reaction over Al-MCM-41",

abstract = "A comprehensive study has been made on the cracking abilities of mesoporous aluminosillicate MCM-41 materials with different Si/Al ratios (15-∞) and pore diameters (1.6-3.0 nm) by using 1,3,5-triisopropylbenzene (1,3,5-TiPB) cracking as the test reaction. The roles of Al ontent and pore diameter on the catalytic features of the samples were evaluated by the conversion of 1,3,5-TiPB, coke content and deactivation parameters. It is found that the catalytic activity is mainly controlled by adsorptive properties towards the reactant and the dispersion of acid sites. In terms of their catalytic performances, cracking reaction over aluminosilicate mesoporous materials is more favorable for catalysts with smaller pore size and higher Al concentration. Moreover, coking is found responsible for atalyst deactivation during 1,3,5-TiPB cracking reaction over Al-MCM-41.",

keywords = "Coking, Confinement effect, Cracking, Mesoporous Al-MCM-41, Pore size, Si/Al ratio",

author = "Chen, {Wen Hua} and Huang, {Shing Jong} and Qi Zhao and Lin, {Hong Ping} and Mou, {Chung Yuan} and Liu, {Shang Bin}",

note = "Funding Information: Acknowledgments The authors thank Professors Soofin Cheng and Ben-Zu Wan for helpful discussions. The financial supports of this research by the National Science Council, Taiwan (NSC95-2113-M-001-040-MY3 and NSC-94-2752-M-002-004-PAE) are also gratefully acknowledged.",

year = "2009",

month = mar,

doi = "10.1007/s11244-008-9139-3",

language = "English",

volume = "52",

pages = "2--11",

journal = "Topics in Catalysis",

issn = "1022-5528",

publisher = "Springer",

number = "1-2",

}

TY - JOUR

T1 - On the confinement effect during catalytic reaction over Al-MCM-41

AU - Chen, Wen Hua

AU - Huang, Shing Jong

AU - Zhao, Qi

AU - Lin, Hong Ping

AU - Mou, Chung Yuan

AU - Liu, Shang Bin

N1 - Funding Information: Acknowledgments The authors thank Professors Soofin Cheng and Ben-Zu Wan for helpful discussions. The financial supports of this research by the National Science Council, Taiwan (NSC95-2113-M-001-040-MY3 and NSC-94-2752-M-002-004-PAE) are also gratefully acknowledged.

PY - 2009/3

Y1 - 2009/3

N2 - A comprehensive study has been made on the cracking abilities of mesoporous aluminosillicate MCM-41 materials with different Si/Al ratios (15-∞) and pore diameters (1.6-3.0 nm) by using 1,3,5-triisopropylbenzene (1,3,5-TiPB) cracking as the test reaction. The roles of Al ontent and pore diameter on the catalytic features of the samples were evaluated by the conversion of 1,3,5-TiPB, coke content and deactivation parameters. It is found that the catalytic activity is mainly controlled by adsorptive properties towards the reactant and the dispersion of acid sites. In terms of their catalytic performances, cracking reaction over aluminosilicate mesoporous materials is more favorable for catalysts with smaller pore size and higher Al concentration. Moreover, coking is found responsible for atalyst deactivation during 1,3,5-TiPB cracking reaction over Al-MCM-41.

AB - A comprehensive study has been made on the cracking abilities of mesoporous aluminosillicate MCM-41 materials with different Si/Al ratios (15-∞) and pore diameters (1.6-3.0 nm) by using 1,3,5-triisopropylbenzene (1,3,5-TiPB) cracking as the test reaction. The roles of Al ontent and pore diameter on the catalytic features of the samples were evaluated by the conversion of 1,3,5-TiPB, coke content and deactivation parameters. It is found that the catalytic activity is mainly controlled by adsorptive properties towards the reactant and the dispersion of acid sites. In terms of their catalytic performances, cracking reaction over aluminosilicate mesoporous materials is more favorable for catalysts with smaller pore size and higher Al concentration. Moreover, coking is found responsible for atalyst deactivation during 1,3,5-TiPB cracking reaction over Al-MCM-41.

KW - Coking

KW - Confinement effect

KW - Cracking

KW - Mesoporous Al-MCM-41

KW - Pore size

KW - Si/Al ratio

UR - http://www.scopus.com/inward/record.url?scp=78049233135&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78049233135&partnerID=8YFLogxK

U2 - 10.1007/s11244-008-9139-3

DO - 10.1007/s11244-008-9139-3

M3 - Article

AN - SCOPUS:78049233135

SN - 1022-5528

VL - 52

SP - 2

EP - 11

JO - Topics in Catalysis

JF - Topics in Catalysis

IS - 1-2

ER -

On the confinement effect during catalytic reaction over Al-MCM-41

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this