Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

Chinnambedu Murugesan Raghavan; Tzu Pei Chen; Shao Sian Li; Wei Liang Chen; Chao Yuan Lo; Yu Ming Liao; Golam Haider; Cheng Chieh Lin; Chia Chun Chen; Raman Sankar; Yu Ming Chang; Fang Cheng Chou; Chun Wei Chen

doi:10.1021/acs.nanolett.8b00990

Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

Chinnambedu Murugesan Raghavan, Tzu Pei Chen, Shao Sian Li, Wei Liang Chen, Chao Yuan Lo, Yu Ming Liao, Golam Haider, Cheng Chieh Lin, Chia Chun Chen, Raman Sankar, Yu Ming Chang, Fang Cheng Chou, Chun Wei Chen

Research output: Contribution to journal › Article › peer-review

137 Citations (Scopus)

Abstract

Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)₂(MA)_-rfnet-1Pb_nI_3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

Original language	English
Pages (from-to)	3221-3228
Number of pages	8
Journal	Nano Letters
Volume	18
Issue number	5
DOIs	https://doi.org/10.1021/acs.nanolett.8b00990
Publication status	Published - May 9 2018

Keywords

2D RPP single crystals
lasing
photoluminescence
solution growth

ASJC Scopus subject areas

Bioengineering
Chemistry(all)
Materials Science(all)
Condensed Matter Physics
Mechanical Engineering

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10.1021/acs.nanolett.8b00990

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@article{a36a2b2f5e284da28ac5a45bebda7477,

title = "Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals",

abstract = "Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)2(MA)-rfnet-1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.",

keywords = "2D RPP single crystals, lasing, photoluminescence, solution growth",

author = "Raghavan, {Chinnambedu Murugesan} and Chen, {Tzu Pei} and Li, {Shao Sian} and Chen, {Wei Liang} and Lo, {Chao Yuan} and Liao, {Yu Ming} and Golam Haider and Lin, {Cheng Chieh} and Chen, {Chia Chun} and Raman Sankar and Chang, {Yu Ming} and Chou, {Fang Cheng} and Chen, {Chun Wei}",

note = "Funding Information: This work is supported by the Ministry of Science and Technology (MOST), Taiwan (Project nos. 105-2112-M-038-001-MY3 and 106-2119-M-002-042-FS) and by the Ministry of Education (MOE), Taiwan (Project no. NTU-107L9008). The authors would like to thank Professor Yang-Fang Chen for the valuable discussion at the Department of Physics, National Taiwan University. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = may,

day = "9",

doi = "10.1021/acs.nanolett.8b00990",

language = "English",

volume = "18",

pages = "3221--3228",

journal = "Nano Letters",

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publisher = "American Chemical Society",

number = "5",

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TY - JOUR

T1 - Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

AU - Raghavan, Chinnambedu Murugesan

AU - Chen, Tzu Pei

AU - Li, Shao Sian

AU - Chen, Wei Liang

AU - Lo, Chao Yuan

AU - Liao, Yu Ming

AU - Haider, Golam

AU - Lin, Cheng Chieh

AU - Chen, Chia Chun

AU - Sankar, Raman

AU - Chang, Yu Ming

AU - Chou, Fang Cheng

AU - Chen, Chun Wei

N1 - Funding Information: This work is supported by the Ministry of Science and Technology (MOST), Taiwan (Project nos. 105-2112-M-038-001-MY3 and 106-2119-M-002-042-FS) and by the Ministry of Education (MOE), Taiwan (Project no. NTU-107L9008). The authors would like to thank Professor Yang-Fang Chen for the valuable discussion at the Department of Physics, National Taiwan University. Publisher Copyright: © 2018 American Chemical Society.

PY - 2018/5/9

Y1 - 2018/5/9

N2 - Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)2(MA)-rfnet-1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

AB - Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)2(MA)-rfnet-1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

KW - 2D RPP single crystals

KW - lasing

KW - photoluminescence

KW - solution growth

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JF - Nano Letters

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Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

Abstract

Keywords

ASJC Scopus subject areas

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