Justicia lignans: Part 10-Synthesis of tiruneesiin, the first neolignan from Justicia species

Gottumukkala V. Subbaraju; Jakka Kavitha; Dodda Rajasekhar; Feng-Lin Hsu; Kur Ta Cheng

Justicia lignans: Part 10-Synthesis of tiruneesiin, the first neolignan from Justicia species

Gottumukkala V. Subbaraju, Jakka Kavitha, Dodda Rajasekhar, Feng-Lin Hsu, Kur Ta Cheng

Research output: Contribution to journal › Article › peer-review

Abstract

(±)-Tiruneesiin, 3-[2-(4-hydroxy-3-methoxyphenyl)-3-acetoxymethyl-7- methoxy-2, 3-dihydro-1-benzofuran-5-yl]propan-1-yl acetate 1, is synthesized starting from methyl ferulate 2 with an overall yield of 12.6%. Ag₂O induced dimerization of 2 is used as a key step in the synthesis.

Original language	English
Pages (from-to)	357-359
Number of pages	3
Journal	Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry
Volume	46
Issue number	2
Publication status	Published - Feb 2007

Keywords

Justicia neesii
Neolignan
Oxidative dimerization
Synthesis
Tiruneesiin

ASJC Scopus subject areas

General Pharmacology, Toxicology and Pharmaceutics
Organic Chemistry

Cite this

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title = "Justicia lignans: Part 10-Synthesis of tiruneesiin, the first neolignan from Justicia species",

abstract = "(±)-Tiruneesiin, 3-[2-(4-hydroxy-3-methoxyphenyl)-3-acetoxymethyl-7- methoxy-2, 3-dihydro-1-benzofuran-5-yl]propan-1-yl acetate 1, is synthesized starting from methyl ferulate 2 with an overall yield of 12.6%. Ag2O induced dimerization of 2 is used as a key step in the synthesis.",

keywords = "Justicia neesii, Neolignan, Oxidative dimerization, Synthesis, Tiruneesiin",

author = "Subbaraju, {Gottumukkala V.} and Jakka Kavitha and Dodda Rajasekhar and Feng-Lin Hsu and Cheng, {Kur Ta}",

year = "2007",

month = feb,

language = "English",

volume = "46",

pages = "357--359",

journal = "Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry",

issn = "0376-4699",

publisher = "Scientific Publishers of India",

number = "2",

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TY - JOUR

T1 - Justicia lignans

T2 - Part 10-Synthesis of tiruneesiin, the first neolignan from Justicia species

AU - Subbaraju, Gottumukkala V.

AU - Kavitha, Jakka

AU - Rajasekhar, Dodda

AU - Hsu, Feng-Lin

AU - Cheng, Kur Ta

PY - 2007/2

Y1 - 2007/2

N2 - (±)-Tiruneesiin, 3-[2-(4-hydroxy-3-methoxyphenyl)-3-acetoxymethyl-7- methoxy-2, 3-dihydro-1-benzofuran-5-yl]propan-1-yl acetate 1, is synthesized starting from methyl ferulate 2 with an overall yield of 12.6%. Ag2O induced dimerization of 2 is used as a key step in the synthesis.

AB - (±)-Tiruneesiin, 3-[2-(4-hydroxy-3-methoxyphenyl)-3-acetoxymethyl-7- methoxy-2, 3-dihydro-1-benzofuran-5-yl]propan-1-yl acetate 1, is synthesized starting from methyl ferulate 2 with an overall yield of 12.6%. Ag2O induced dimerization of 2 is used as a key step in the synthesis.

KW - Justicia neesii

KW - Neolignan

KW - Oxidative dimerization

KW - Synthesis

KW - Tiruneesiin

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M3 - Article

AN - SCOPUS:34548230986

SN - 0376-4699

VL - 46

SP - 357

EP - 359

JO - Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry

JF - Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry

IS - 2

ER -

Justicia lignans: Part 10-Synthesis of tiruneesiin, the first neolignan from Justicia species

Abstract

Keywords

ASJC Scopus subject areas

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