Interaction of copper(I)-polypyrrole complexes prepared by depositing-dissolving copper onto and from polypyrroles

Y. C. Liu; B. J. Hwang

doi:10.1016/S0040-6090(98)01322-4

Interaction of copper(I)-polypyrrole complexes prepared by depositing-dissolving copper onto and from polypyrroles

Y. C. Liu, B. J. Hwang

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Interaction of copper(I)-polypyrrole (PPy) complexes prepared by dissolving excess bulk Cu from PPy and leaving the Cu⁺ within PPy was investigated. The Cu-PPy interaction resulting from an electron transfer from the Cu atom to the PPy was determined from surface-enhanced Raman spectroscopy (SERS) and X-ray photoelectron spectroscopy (XPS) analyses. There is one Cu⁺ for circa 6 pyrrole monomers estimated from the difference of the charges of Cu deposition and dissolution, the dissolving curves of cyclic voltammetry (CV) voltammograms, and the XPS analysis.

Original language	English
Pages (from-to)	233-239
Number of pages	7
Journal	Thin Solid Films
Volume	339
Issue number	1-2
DOIs	https://doi.org/10.1016/S0040-6090(98)01322-4
Publication status	Published - 1999
Externally published	Yes

Keywords

Complex
Interaction
Surface-enhanced Raman spectroscopy
X-ray photoelectron spectroscopy

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Surfaces and Interfaces

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10.1016/S0040-6090(98)01322-4

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abstract = "Interaction of copper(I)-polypyrrole (PPy) complexes prepared by dissolving excess bulk Cu from PPy and leaving the Cu+ within PPy was investigated. The Cu-PPy interaction resulting from an electron transfer from the Cu atom to the PPy was determined from surface-enhanced Raman spectroscopy (SERS) and X-ray photoelectron spectroscopy (XPS) analyses. There is one Cu+ for circa 6 pyrrole monomers estimated from the difference of the charges of Cu deposition and dissolution, the dissolving curves of cyclic voltammetry (CV) voltammograms, and the XPS analysis.",

keywords = "Complex, Interaction, Surface-enhanced Raman spectroscopy, X-ray photoelectron spectroscopy",

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year = "1999",

doi = "10.1016/S0040-6090(98)01322-4",

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pages = "233--239",

journal = "Thin Solid Films",

issn = "0040-6090",

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number = "1-2",

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T1 - Interaction of copper(I)-polypyrrole complexes prepared by depositing-dissolving copper onto and from polypyrroles

AU - Liu, Y. C.

AU - Hwang, B. J.

PY - 1999

Y1 - 1999

N2 - Interaction of copper(I)-polypyrrole (PPy) complexes prepared by dissolving excess bulk Cu from PPy and leaving the Cu+ within PPy was investigated. The Cu-PPy interaction resulting from an electron transfer from the Cu atom to the PPy was determined from surface-enhanced Raman spectroscopy (SERS) and X-ray photoelectron spectroscopy (XPS) analyses. There is one Cu+ for circa 6 pyrrole monomers estimated from the difference of the charges of Cu deposition and dissolution, the dissolving curves of cyclic voltammetry (CV) voltammograms, and the XPS analysis.

AB - Interaction of copper(I)-polypyrrole (PPy) complexes prepared by dissolving excess bulk Cu from PPy and leaving the Cu+ within PPy was investigated. The Cu-PPy interaction resulting from an electron transfer from the Cu atom to the PPy was determined from surface-enhanced Raman spectroscopy (SERS) and X-ray photoelectron spectroscopy (XPS) analyses. There is one Cu+ for circa 6 pyrrole monomers estimated from the difference of the charges of Cu deposition and dissolution, the dissolving curves of cyclic voltammetry (CV) voltammograms, and the XPS analysis.

KW - Complex

KW - Interaction

KW - Surface-enhanced Raman spectroscopy

KW - X-ray photoelectron spectroscopy

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DO - 10.1016/S0040-6090(98)01322-4

M3 - Article

AN - SCOPUS:0033534971

SN - 0040-6090

VL - 339

SP - 233

EP - 239

JO - Thin Solid Films

JF - Thin Solid Films

IS - 1-2

ER -

Interaction of copper(I)-polypyrrole complexes prepared by depositing-dissolving copper onto and from polypyrroles

Abstract

Keywords

ASJC Scopus subject areas

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