Ga-promoted tungstated zirconia catalyst for n-butane isomerization

Xiao Rong Chen; Chang Lin Chen; Nan Ping Xu; Song Han; Chung Yuan Mou

doi:10.1023/A:1022137612328

Ga-promoted tungstated zirconia catalyst for n-butane isomerization

Xiao Rong Chen, Chang Lin Chen, Nan Ping Xu, Song Han, Chung Yuan Mou

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N₂ adsorption, NH₃ temperature-programmed desorption (NH₃ TPD), microcalorimetry and H₂ temperature-programmed reduction (H₂ TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.

Original language	English
Pages (from-to)	177-182
Number of pages	6
Journal	Catalysis Letters
Volume	85
Issue number	3-4
DOIs	https://doi.org/10.1023/A:1022137612328
Publication status	Published - Feb 2003
Externally published	Yes

Keywords

Gallium
N-butane isomerization
Tungstated zirconia

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1023/A:1022137612328

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title = "Ga-promoted tungstated zirconia catalyst for n-butane isomerization",

abstract = "Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N2 adsorption, NH3 temperature-programmed desorption (NH3 TPD), microcalorimetry and H2 temperature-programmed reduction (H2 TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.",

keywords = "Gallium, N-butane isomerization, Tungstated zirconia",

author = "Chen, \{Xiao Rong\} and Chen, \{Chang Lin\} and Xu, \{Nan Ping\} and Song Han and Mou, \{Chung Yuan\}",

note = "Funding Information: We thank Professor Jianyi Shen from Nanjing University for help in the microcalorimetric study. Financial support from the Educational Department of Jiangsu Province (Project 00KJB530001 to CLC), the Science and Technology Department of Jiangsu Province (Project GB2002017 to CLC), and Key Laboratory of Chemical Engineering and Technology of Jiangsu Province is gratefully acknowledged.",

year = "2003",

month = feb,

doi = "10.1023/A:1022137612328",

language = "English",

volume = "85",

pages = "177--182",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "3-4",

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TY - JOUR

T1 - Ga-promoted tungstated zirconia catalyst for n-butane isomerization

AU - Chen, Xiao Rong

AU - Chen, Chang Lin

AU - Xu, Nan Ping

AU - Han, Song

AU - Mou, Chung Yuan

N1 - Funding Information: We thank Professor Jianyi Shen from Nanjing University for help in the microcalorimetric study. Financial support from the Educational Department of Jiangsu Province (Project 00KJB530001 to CLC), the Science and Technology Department of Jiangsu Province (Project GB2002017 to CLC), and Key Laboratory of Chemical Engineering and Technology of Jiangsu Province is gratefully acknowledged.

PY - 2003/2

Y1 - 2003/2

N2 - Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N2 adsorption, NH3 temperature-programmed desorption (NH3 TPD), microcalorimetry and H2 temperature-programmed reduction (H2 TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.

AB - Ga-promoted tungstated zirconia (GWZ) was prepared by a slurry impregnation method. The textural properties as well as the acidities of the Ga-promoted catalysts were characterized by X-ray powder diffraction (XRD), N2 adsorption, NH3 temperature-programmed desorption (NH3 TPD), microcalorimetry and H2 temperature-programmed reduction (H2 TPR). The catalytic behavior of GWZ for n-butane isomerization was studied in the presence of hydrogen. In comparison to tungstated zirconia (WZ), the catalytic activity of the Ga-promoted catalyst was greatly improved. The reason proposed for the higher activity of the Ga-promoted catalysts was that Ga enhances the oxidizing ability of the catalysts.

KW - Gallium

KW - N-butane isomerization

KW - Tungstated zirconia

UR - https://www.scopus.com/pages/publications/0037297263

UR - https://www.scopus.com/inward/citedby.url?scp=0037297263&partnerID=8YFLogxK

U2 - 10.1023/A:1022137612328

DO - 10.1023/A:1022137612328

M3 - Article

AN - SCOPUS:0037297263

SN - 1011-372X

VL - 85

SP - 177

EP - 182

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Ga-promoted tungstated zirconia catalyst for n-butane isomerization

Abstract

Keywords

ASJC Scopus subject areas

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