Facile synthesis of copper cobalt sulfide and nickel hydroxide tube-like composites as battery-type active material of energy storage devices

Tsung Rong Kuo; Istikhori Fitriannisa; Ren Jei Chung; Kuan Hsien Lin; Sibidou Yougbaré; Lu Yin Lin; Yung Fu Wu

doi:10.1016/j.est.2023.107330

Facile synthesis of copper cobalt sulfide and nickel hydroxide tube-like composites as battery-type active material of energy storage devices

Tsung Rong Kuo, Istikhori Fitriannisa, Ren Jei Chung, Kuan Hsien Lin, Sibidou Yougbaré, Lu Yin Lin, Yung Fu Wu

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Bimetallic sulfide has attracted much attentions as efficient electroactive materials of battery supercapacitor hybrid (BSH), because of numerous redox states, high conductivity and good energy efficiency. Developing composites having excellent chemical and electrochemical properties is necessary to enhance the energy storage features of bimetallic sulfides. In this study, CuCo₂S₄ and Ni(OH)₂ composites (CuCo₂S₄@Ni(OH)₂) are designed on Ni foam via the facial hydrothermal process and chemical bath deposition as the electroactive material of BSH at first time. Effects of Ni(OH)₂ amounts on CuCo₂S₄ on electrochemical and physical properties of CuCo₂S₄@Ni(OH)₂ are investigated. The physical mixed CuCo₂S₄ and Ni(OH)₂ composite is also fabricated to verify synergistic effects of CuCo₂S₄@Ni(OH)₂. A higher specific capacitance (C_F) of 1583.9 F/g along with the capacity of 220.0 mAh/g are got for optimal CuCo₂S₄@Ni(OH)₂ electrode, respectively comparing to 831.7 and 1063.3 F/g of CuCoS₄ and Ni(OH)₂ electrodes. A BSH is fabricated by the CuCo₂S₄@Ni(OH)₂ electrode and the activated carbon electrode. The potential window of 1.6 V and maximum energy density of 32.1 Wh/kg at 1.1 kW/kg are achieved. The C_F retention of 78% and Coulombic efficiency higher than 97% in 8000 charge/discharge cycles are also obtained for this BSH.

Original language	English
Article number	107330
Journal	Journal of Energy Storage
Volume	65
DOIs	https://doi.org/10.1016/j.est.2023.107330
Publication status	Published - Aug 15 2023

Keywords

Battery supercapacitor hybrid
Bimetallic sulfide
Copper cobalt sulfide
Hydrothermal
Nickel hydroxide
Synergistic effect

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.est.2023.107330

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title = "Facile synthesis of copper cobalt sulfide and nickel hydroxide tube-like composites as battery-type active material of energy storage devices",

abstract = "Bimetallic sulfide has attracted much attentions as efficient electroactive materials of battery supercapacitor hybrid (BSH), because of numerous redox states, high conductivity and good energy efficiency. Developing composites having excellent chemical and electrochemical properties is necessary to enhance the energy storage features of bimetallic sulfides. In this study, CuCo2S4 and Ni(OH)2 composites (CuCo2S4@Ni(OH)2) are designed on Ni foam via the facial hydrothermal process and chemical bath deposition as the electroactive material of BSH at first time. Effects of Ni(OH)2 amounts on CuCo2S4 on electrochemical and physical properties of CuCo2S4@Ni(OH)2 are investigated. The physical mixed CuCo2S4 and Ni(OH)2 composite is also fabricated to verify synergistic effects of CuCo2S4@Ni(OH)2. A higher specific capacitance (CF) of 1583.9 F/g along with the capacity of 220.0 mAh/g are got for optimal CuCo2S4@Ni(OH)2 electrode, respectively comparing to 831.7 and 1063.3 F/g of CuCoS4 and Ni(OH)2 electrodes. A BSH is fabricated by the CuCo2S4@Ni(OH)2 electrode and the activated carbon electrode. The potential window of 1.6 V and maximum energy density of 32.1 Wh/kg at 1.1 kW/kg are achieved. The CF retention of 78% and Coulombic efficiency higher than 97% in 8000 charge/discharge cycles are also obtained for this BSH.",

keywords = "Battery supercapacitor hybrid, Bimetallic sulfide, Copper cobalt sulfide, Hydrothermal, Nickel hydroxide, Synergistic effect",

author = "Kuo, {Tsung Rong} and Istikhori Fitriannisa and Chung, {Ren Jei} and Lin, {Kuan Hsien} and Sibidou Yougbar{\'e} and Lin, {Lu Yin} and Wu, {Yung Fu}",

note = "Funding Information: This work was assisted by Precision Analysis and Material Research Center, NTUT. This work was also financially supported by National Science and Technology Council (NSTC) in Taiwan, under Grant 111-2221-E-027-071-MY3 . This work was supported by University System of Taipei Joint Research Program ( USTP-NTUT-TMU-112-01 ). Publisher Copyright: {\textcopyright} 2023",

year = "2023",

month = aug,

day = "15",

doi = "10.1016/j.est.2023.107330",

language = "English",

volume = "65",

journal = "Journal of Energy Storage",

issn = "2352-152X",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Facile synthesis of copper cobalt sulfide and nickel hydroxide tube-like composites as battery-type active material of energy storage devices

AU - Kuo, Tsung Rong

AU - Fitriannisa, Istikhori

AU - Chung, Ren Jei

AU - Lin, Kuan Hsien

AU - Yougbaré, Sibidou

AU - Lin, Lu Yin

AU - Wu, Yung Fu

N1 - Funding Information: This work was assisted by Precision Analysis and Material Research Center, NTUT. This work was also financially supported by National Science and Technology Council (NSTC) in Taiwan, under Grant 111-2221-E-027-071-MY3 . This work was supported by University System of Taipei Joint Research Program ( USTP-NTUT-TMU-112-01 ). Publisher Copyright: © 2023

PY - 2023/8/15

Y1 - 2023/8/15

N2 - Bimetallic sulfide has attracted much attentions as efficient electroactive materials of battery supercapacitor hybrid (BSH), because of numerous redox states, high conductivity and good energy efficiency. Developing composites having excellent chemical and electrochemical properties is necessary to enhance the energy storage features of bimetallic sulfides. In this study, CuCo2S4 and Ni(OH)2 composites (CuCo2S4@Ni(OH)2) are designed on Ni foam via the facial hydrothermal process and chemical bath deposition as the electroactive material of BSH at first time. Effects of Ni(OH)2 amounts on CuCo2S4 on electrochemical and physical properties of CuCo2S4@Ni(OH)2 are investigated. The physical mixed CuCo2S4 and Ni(OH)2 composite is also fabricated to verify synergistic effects of CuCo2S4@Ni(OH)2. A higher specific capacitance (CF) of 1583.9 F/g along with the capacity of 220.0 mAh/g are got for optimal CuCo2S4@Ni(OH)2 electrode, respectively comparing to 831.7 and 1063.3 F/g of CuCoS4 and Ni(OH)2 electrodes. A BSH is fabricated by the CuCo2S4@Ni(OH)2 electrode and the activated carbon electrode. The potential window of 1.6 V and maximum energy density of 32.1 Wh/kg at 1.1 kW/kg are achieved. The CF retention of 78% and Coulombic efficiency higher than 97% in 8000 charge/discharge cycles are also obtained for this BSH.

AB - Bimetallic sulfide has attracted much attentions as efficient electroactive materials of battery supercapacitor hybrid (BSH), because of numerous redox states, high conductivity and good energy efficiency. Developing composites having excellent chemical and electrochemical properties is necessary to enhance the energy storage features of bimetallic sulfides. In this study, CuCo2S4 and Ni(OH)2 composites (CuCo2S4@Ni(OH)2) are designed on Ni foam via the facial hydrothermal process and chemical bath deposition as the electroactive material of BSH at first time. Effects of Ni(OH)2 amounts on CuCo2S4 on electrochemical and physical properties of CuCo2S4@Ni(OH)2 are investigated. The physical mixed CuCo2S4 and Ni(OH)2 composite is also fabricated to verify synergistic effects of CuCo2S4@Ni(OH)2. A higher specific capacitance (CF) of 1583.9 F/g along with the capacity of 220.0 mAh/g are got for optimal CuCo2S4@Ni(OH)2 electrode, respectively comparing to 831.7 and 1063.3 F/g of CuCoS4 and Ni(OH)2 electrodes. A BSH is fabricated by the CuCo2S4@Ni(OH)2 electrode and the activated carbon electrode. The potential window of 1.6 V and maximum energy density of 32.1 Wh/kg at 1.1 kW/kg are achieved. The CF retention of 78% and Coulombic efficiency higher than 97% in 8000 charge/discharge cycles are also obtained for this BSH.

KW - Battery supercapacitor hybrid

KW - Bimetallic sulfide

KW - Copper cobalt sulfide

KW - Hydrothermal

KW - Nickel hydroxide

KW - Synergistic effect

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U2 - 10.1016/j.est.2023.107330

DO - 10.1016/j.est.2023.107330

M3 - Article

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SN - 2352-152X

VL - 65

JO - Journal of Energy Storage

JF - Journal of Energy Storage

M1 - 107330

ER -

Facile synthesis of copper cobalt sulfide and nickel hydroxide tube-like composites as battery-type active material of energy storage devices

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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