Effect of precursor characteristics on zirconia and ceria particle morphology in spray pyrolysis

C. Y. Chen; T. K. Tseng; S. C. Tsai; C. K. Lin; H. M. Lin

doi:10.1016/j.ceramint.2006.10.013

Effect of precursor characteristics on zirconia and ceria particle morphology in spray pyrolysis

C. Y. Chen, T. K. Tseng, S. C. Tsai, C. K. Lin, H. M. Lin

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

Ultrasonic spray pyrolysis of acetate-based precursors with precisely measured precursor drop size was employed to produce ZrO₂ and CeO₂ particles. A bimodal size distribution of the product particles indicates a significant influence of the gas-to-particle conversion mechanism in addition to the conventionally accepted one-particle-per-drop mechanism. Due to the differences in solubility of the precursors, ZrO₂ particles are spherical in shape and smooth on their surfaces while the CeO₂ particles are bowl-like in shape with uneven surfaces. Spherical and monodispersed particles with a peak diameter

Original language	English
Pages (from-to)	409-416
Number of pages	8
Journal	Ceramics International
Volume	34
Issue number	2
DOIs	https://doi.org/10.1016/j.ceramint.2006.10.013
Publication status	Published - Mar 2008
Externally published	Yes

Keywords

A. Powders: Chemical preparation
A. Precursors: organic
D. CeO
D. ZrO
Microstructure
Spray pyrolysis

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Process Chemistry and Technology
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/j.ceramint.2006.10.013

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title = "Effect of precursor characteristics on zirconia and ceria particle morphology in spray pyrolysis",

abstract = "Ultrasonic spray pyrolysis of acetate-based precursors with precisely measured precursor drop size was employed to produce ZrO2 and CeO2 particles. A bimodal size distribution of the product particles indicates a significant influence of the gas-to-particle conversion mechanism in addition to the conventionally accepted one-particle-per-drop mechanism. Due to the differences in solubility of the precursors, ZrO2 particles are spherical in shape and smooth on their surfaces while the CeO2 particles are bowl-like in shape with uneven surfaces. Spherical and monodispersed particles with a peak diameter ",

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author = "Chen, \{C. Y.\} and Tseng, \{T. K.\} and Tsai, \{S. C.\} and Lin, \{C. K.\} and Lin, \{H. M.\}",

year = "2008",

month = mar,

doi = "10.1016/j.ceramint.2006.10.013",

language = "English",

volume = "34",

pages = "409--416",

journal = "Ceramics International",

issn = "0272-8842",

publisher = "Elsevier Ltd",

number = "2",

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TY - JOUR

T1 - Effect of precursor characteristics on zirconia and ceria particle morphology in spray pyrolysis

AU - Chen, C. Y.

AU - Tseng, T. K.

AU - Tsai, S. C.

AU - Lin, C. K.

AU - Lin, H. M.

PY - 2008/3

Y1 - 2008/3

N2 - Ultrasonic spray pyrolysis of acetate-based precursors with precisely measured precursor drop size was employed to produce ZrO2 and CeO2 particles. A bimodal size distribution of the product particles indicates a significant influence of the gas-to-particle conversion mechanism in addition to the conventionally accepted one-particle-per-drop mechanism. Due to the differences in solubility of the precursors, ZrO2 particles are spherical in shape and smooth on their surfaces while the CeO2 particles are bowl-like in shape with uneven surfaces. Spherical and monodispersed particles with a peak diameter

AB - Ultrasonic spray pyrolysis of acetate-based precursors with precisely measured precursor drop size was employed to produce ZrO2 and CeO2 particles. A bimodal size distribution of the product particles indicates a significant influence of the gas-to-particle conversion mechanism in addition to the conventionally accepted one-particle-per-drop mechanism. Due to the differences in solubility of the precursors, ZrO2 particles are spherical in shape and smooth on their surfaces while the CeO2 particles are bowl-like in shape with uneven surfaces. Spherical and monodispersed particles with a peak diameter

KW - A. Powders: Chemical preparation

KW - A. Precursors: organic

KW - D. CeO

KW - D. ZrO

KW - Microstructure

KW - Spray pyrolysis

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U2 - 10.1016/j.ceramint.2006.10.013

DO - 10.1016/j.ceramint.2006.10.013

M3 - Article

AN - SCOPUS:38149109730

SN - 0272-8842

VL - 34

SP - 409

EP - 416

JO - Ceramics International

JF - Ceramics International

IS - 2

ER -

Effect of precursor characteristics on zirconia and ceria particle morphology in spray pyrolysis

Abstract

Keywords

ASJC Scopus subject areas

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