Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones

Jun You Chen; Szu Chien Chen; Yun Ju Tang; Chung Yuan Mou; Fu Yu Tsai

doi:10.1016/j.molcata.2009.03.014

Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones

Jun You Chen, Szu Chien Chen, Yun Ju Tang, Chung Yuan Mou, Fu Yu Tsai

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

The coupling reactions of acyl chlorides with triarylbismuths catalyzed by a palladium bipyridyl complex anchored on nanosized mesoporous silica MCM-41 gave diaryl and alkyl aryl ketones in good to high yields. The amount of triarylbismuths required for the cross-coupling could be up to half the molar ratio relative to the acyl chlorides for the completion of the reaction; the catalyst could be recovered and re-used after the reaction, providing both an atom-efficient and catalyst-recyclable process for the synthesis of diaryl and alkyl aryl ketones.

Original language	English
Pages (from-to)	88-92
Number of pages	5
Journal	Journal of Molecular Catalysis A: Chemical
Volume	307
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2009.03.014
Publication status	Published - Jul 15 2009
Externally published	Yes

Keywords

Cross-coupling
Ketones
Mesoporous silica
Palladium complex
Recyclable catalyst

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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Chen, J. Y., Chen, S. C., Tang, Y. J., Mou, C. Y., & Tsai, F. Y. (2009). Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones. Journal of Molecular Catalysis A: Chemical, 307(1-2), 88-92. https://doi.org/10.1016/j.molcata.2009.03.014

Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones. / Chen, Jun You; Chen, Szu Chien; Tang, Yun Ju et al.
In: Journal of Molecular Catalysis A: Chemical, Vol. 307, No. 1-2, 15.07.2009, p. 88-92.

Research output: Contribution to journal › Article › peer-review

Chen, JY, Chen, SC, Tang, YJ, Mou, CY & Tsai, FY 2009, 'Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones', Journal of Molecular Catalysis A: Chemical, vol. 307, no. 1-2, pp. 88-92. https://doi.org/10.1016/j.molcata.2009.03.014

Chen JY, Chen SC, Tang YJ, Mou CY, Tsai FY. Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones. Journal of Molecular Catalysis A: Chemical. 2009 Jul 15;307(1-2):88-92. doi: 10.1016/j.molcata.2009.03.014

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title = "Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones",

abstract = "The coupling reactions of acyl chlorides with triarylbismuths catalyzed by a palladium bipyridyl complex anchored on nanosized mesoporous silica MCM-41 gave diaryl and alkyl aryl ketones in good to high yields. The amount of triarylbismuths required for the cross-coupling could be up to half the molar ratio relative to the acyl chlorides for the completion of the reaction; the catalyst could be recovered and re-used after the reaction, providing both an atom-efficient and catalyst-recyclable process for the synthesis of diaryl and alkyl aryl ketones.",

keywords = "Cross-coupling, Ketones, Mesoporous silica, Palladium complex, Recyclable catalyst",

author = "Chen, {Jun You} and Chen, {Szu Chien} and Tang, {Yun Ju} and Mou, {Chung Yuan} and Tsai, {Fu Yu}",

note = "Funding Information: This research was financially supported by the National Science Council of Taiwan (NSC95-2113-M-027-001). ",

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AU - Chen, Jun You

AU - Chen, Szu Chien

AU - Tang, Yun Ju

AU - Mou, Chung Yuan

AU - Tsai, Fu Yu

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AB - The coupling reactions of acyl chlorides with triarylbismuths catalyzed by a palladium bipyridyl complex anchored on nanosized mesoporous silica MCM-41 gave diaryl and alkyl aryl ketones in good to high yields. The amount of triarylbismuths required for the cross-coupling could be up to half the molar ratio relative to the acyl chlorides for the completion of the reaction; the catalyst could be recovered and re-used after the reaction, providing both an atom-efficient and catalyst-recyclable process for the synthesis of diaryl and alkyl aryl ketones.

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KW - Mesoporous silica

KW - Palladium complex

KW - Recyclable catalyst

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Coupling of acyl chlorides with triarylbismuths catalyzed by palladium bipyridyl complex anchored on nanosized MCM-41: A recyclable and atom-efficient catalytic process for the synthesis of diaryl and alkyl aryl ketones

Abstract

Keywords

ASJC Scopus subject areas

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