Converting hcp Mg-Al-Zn alloy into bcc Mg-Li-Al-Zn alloy by electrolytic deposition and diffusion of reduced lithium atoms in a molten salt electrolyte LiCl-KCl

M. C. Lin; C. Y. Tsai; J. Y. Uan

doi:10.1016/j.scriptamat.2006.12.017

Converting hcp Mg-Al-Zn alloy into bcc Mg-Li-Al-Zn alloy by electrolytic deposition and diffusion of reduced lithium atoms in a molten salt electrolyte LiCl-KCl

M. C. Lin, C. Y. Tsai, J. Y. Uan

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500 °C. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12 wt.% Li and only 0.264 wt.% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.

Original language	English
Pages (from-to)	597-600
Number of pages	4
Journal	Scripta Materialia
Volume	56
Issue number	7
DOIs	https://doi.org/10.1016/j.scriptamat.2006.12.017
Publication status	Published - Apr 2007
Externally published	Yes

Keywords

Deposition
Diffusion
Electrolysis
hcp → bcc
Mg-Li alloy

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys

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10.1016/j.scriptamat.2006.12.017

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title = "Converting hcp Mg-Al-Zn alloy into bcc Mg-Li-Al-Zn alloy by electrolytic deposition and diffusion of reduced lithium atoms in a molten salt electrolyte LiCl-KCl",

abstract = "A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.\%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500 °C. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12 wt.\% Li and only 0.264 wt.\% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47\% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.",

keywords = "Deposition, Diffusion, Electrolysis, hcp → bcc, Mg-Li alloy",

author = "Lin, \{M. C.\} and Tsai, \{C. Y.\} and Uan, \{J. Y.\}",

year = "2007",

month = apr,

doi = "10.1016/j.scriptamat.2006.12.017",

language = "English",

volume = "56",

pages = "597--600",

journal = "Scripta Materialia",

issn = "1359-6462",

publisher = "Acta Materialia Inc",

number = "7",

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TY - JOUR

T1 - Converting hcp Mg-Al-Zn alloy into bcc Mg-Li-Al-Zn alloy by electrolytic deposition and diffusion of reduced lithium atoms in a molten salt electrolyte LiCl-KCl

AU - Lin, M. C.

AU - Tsai, C. Y.

AU - Uan, J. Y.

PY - 2007/4

Y1 - 2007/4

N2 - A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500 °C. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12 wt.% Li and only 0.264 wt.% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.

AB - A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500 °C. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12 wt.% Li and only 0.264 wt.% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.

KW - Deposition

KW - Diffusion

KW - Electrolysis

KW - hcp → bcc

KW - Mg-Li alloy

UR - https://www.scopus.com/pages/publications/33846544913

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U2 - 10.1016/j.scriptamat.2006.12.017

DO - 10.1016/j.scriptamat.2006.12.017

M3 - Article

AN - SCOPUS:33846544913

SN - 1359-6462

VL - 56

SP - 597

EP - 600

JO - Scripta Materialia

JF - Scripta Materialia

IS - 7

ER -

Converting hcp Mg-Al-Zn alloy into bcc Mg-Li-Al-Zn alloy by electrolytic deposition and diffusion of reduced lithium atoms in a molten salt electrolyte LiCl-KCl

Abstract

Keywords

ASJC Scopus subject areas

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