Combination of carboxymethyl chitosan-coated magnetic nanoparticles and chitosan-citrate complex gel beads as a novel magnetic adsorbent

Fwu Long Mi; Shao Jung Wu; Yung Chih Chen

doi:10.1016/j.carbpol.2015.06.031

Combination of carboxymethyl chitosan-coated magnetic nanoparticles and chitosan-citrate complex gel beads as a novel magnetic adsorbent

Fwu Long Mi, Shao Jung Wu, Yung Chih Chen

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

Abstract Magnetic chitosan beads were synthesized by incorporating N,O-carboxymethyl chitosan-coated magnetic nanoparticles (NOCC-MNPs) into chitosan-citrate gel beads (CCGBs) for adsorbing Cu(II) ions. An increase of Cu(II) adsorption capacity was due to the combined chelation effects from the electron-donating functional groups in the CCGBs and NOCC-MNPs. Moreover, the paramagnetic susceptibility of Cu(II) citrate chelates could further improve the Cu(II) adsorption efficiency through the force of magnetic attraction. The adsorption data of the magnetic CCGBs fitted well with the Freundlich model, whereas the adsorption kinetics followed the pseudo-second-order kinetic model. The maximal adsorption capacity as estimated by the Langmuir model was 294.11 mg/g. The adsorption thermodynamic parameters indicated that the involved process should be spontaneous and exothermic.

Original language	English
Article number	10019
Pages (from-to)	255-263
Number of pages	9
Journal	Carbohydrate Polymers
Volume	131
DOIs	https://doi.org/10.1016/j.carbpol.2015.06.031
Publication status	Published - Jun 25 2015

Keywords

Adsorption
Chitosan
Citrate
Magnetic nanoparticles

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/j.carbpol.2015.06.031

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@article{be31e8898d7b46b2958e2aa88d3a0714,

title = "Combination of carboxymethyl chitosan-coated magnetic nanoparticles and chitosan-citrate complex gel beads as a novel magnetic adsorbent",

abstract = "Abstract Magnetic chitosan beads were synthesized by incorporating N,O-carboxymethyl chitosan-coated magnetic nanoparticles (NOCC-MNPs) into chitosan-citrate gel beads (CCGBs) for adsorbing Cu(II) ions. An increase of Cu(II) adsorption capacity was due to the combined chelation effects from the electron-donating functional groups in the CCGBs and NOCC-MNPs. Moreover, the paramagnetic susceptibility of Cu(II) citrate chelates could further improve the Cu(II) adsorption efficiency through the force of magnetic attraction. The adsorption data of the magnetic CCGBs fitted well with the Freundlich model, whereas the adsorption kinetics followed the pseudo-second-order kinetic model. The maximal adsorption capacity as estimated by the Langmuir model was 294.11 mg/g. The adsorption thermodynamic parameters indicated that the involved process should be spontaneous and exothermic.",

keywords = "Adsorption, Chitosan, Citrate, Magnetic nanoparticles",

author = "Mi, {Fwu Long} and Wu, {Shao Jung} and Chen, {Yung Chih}",

note = "Funding Information: The authors gratefully acknowledge the financial support provided by the Ministry of Science and Technology (NSC 100-2221-E-131-013), Taiwan, ROC.",

year = "2015",

month = jun,

day = "25",

doi = "10.1016/j.carbpol.2015.06.031",

language = "English",

volume = "131",

pages = "255--263",

journal = "Carbohydrate Polymers",

issn = "0144-8617",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Combination of carboxymethyl chitosan-coated magnetic nanoparticles and chitosan-citrate complex gel beads as a novel magnetic adsorbent

AU - Mi, Fwu Long

AU - Wu, Shao Jung

AU - Chen, Yung Chih

N1 - Funding Information: The authors gratefully acknowledge the financial support provided by the Ministry of Science and Technology (NSC 100-2221-E-131-013), Taiwan, ROC.

PY - 2015/6/25

Y1 - 2015/6/25

N2 - Abstract Magnetic chitosan beads were synthesized by incorporating N,O-carboxymethyl chitosan-coated magnetic nanoparticles (NOCC-MNPs) into chitosan-citrate gel beads (CCGBs) for adsorbing Cu(II) ions. An increase of Cu(II) adsorption capacity was due to the combined chelation effects from the electron-donating functional groups in the CCGBs and NOCC-MNPs. Moreover, the paramagnetic susceptibility of Cu(II) citrate chelates could further improve the Cu(II) adsorption efficiency through the force of magnetic attraction. The adsorption data of the magnetic CCGBs fitted well with the Freundlich model, whereas the adsorption kinetics followed the pseudo-second-order kinetic model. The maximal adsorption capacity as estimated by the Langmuir model was 294.11 mg/g. The adsorption thermodynamic parameters indicated that the involved process should be spontaneous and exothermic.

AB - Abstract Magnetic chitosan beads were synthesized by incorporating N,O-carboxymethyl chitosan-coated magnetic nanoparticles (NOCC-MNPs) into chitosan-citrate gel beads (CCGBs) for adsorbing Cu(II) ions. An increase of Cu(II) adsorption capacity was due to the combined chelation effects from the electron-donating functional groups in the CCGBs and NOCC-MNPs. Moreover, the paramagnetic susceptibility of Cu(II) citrate chelates could further improve the Cu(II) adsorption efficiency through the force of magnetic attraction. The adsorption data of the magnetic CCGBs fitted well with the Freundlich model, whereas the adsorption kinetics followed the pseudo-second-order kinetic model. The maximal adsorption capacity as estimated by the Langmuir model was 294.11 mg/g. The adsorption thermodynamic parameters indicated that the involved process should be spontaneous and exothermic.

KW - Adsorption

KW - Chitosan

KW - Citrate

KW - Magnetic nanoparticles

UR - http://www.scopus.com/inward/record.url?scp=84935012490&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84935012490&partnerID=8YFLogxK

U2 - 10.1016/j.carbpol.2015.06.031

DO - 10.1016/j.carbpol.2015.06.031

M3 - Article

C2 - 26256183

AN - SCOPUS:84935012490

SN - 0144-8617

VL - 131

SP - 255

EP - 263

JO - Carbohydrate Polymers

JF - Carbohydrate Polymers

M1 - 10019

ER -

Combination of carboxymethyl chitosan-coated magnetic nanoparticles and chitosan-citrate complex gel beads as a novel magnetic adsorbent

Abstract

Keywords

ASJC Scopus subject areas

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