Co2+-Doped BiOBrxCl1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli

Er-Chieh Cho; Cai-Wan Chang-Jian; Jen-Hsien Huang; Guang-Yu Lee; Wei-Hung Hung; Ming-Yen Sung; Kuen-Chan Lee; Huei Chu Weng; Wei-Lin Syu; Yu-Sheng Hsiao; Chih-Ping Chen

doi:10.1016/j.jhazmat.2020.123457

Co²⁺-Doped BiOBr_xCl_1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli

Er-Chieh Cho, Cai-Wan Chang-Jian, Jen-Hsien Huang, Guang-Yu Lee, Wei-Hung Hung, Ming-Yen Sung, Kuen-Chan Lee, Huei Chu Weng, Wei-Lin Syu, Yu-Sheng Hsiao, Chih-Ping Chen

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

In this article, we have synthesized Co²⁺-doped BiOBr_xCl_1-x hierarchical nanostructured microspheres, featuring different degrees of Co²⁺ doping, displaying excellent photocatalytic performance. X-ray diffraction and Raman spectroscopy indicated that the Co²⁺ ions were successfully doped into the BiOBr_xCl_1-x nanocrystals. The photodegradation rate of rhodamine B mediated by a doped BiOBr_xCl_1-x was 150 % greater than that of the non-doped BiOBr. We ascribe the improved photocatalytic capability of the Co²⁺-doped BiOBr_xCl_1-x to a combination of its superior degree of light absorption, more efficient carrier separation, and faster interfacial charge migration. The major active species involved in the photodegradation of RhB also has been investigated. Moreover, the doped BiOBr_xCl_1-x possessed excellent cellular biocompatibility and displayed remarkable performance in the photocatalytic bacterial inactivation.

Original language	English
Article number	123457
Pages (from-to)	123457
Journal	Journal of Hazardous Materials
Volume	402
DOIs	https://doi.org/10.1016/j.jhazmat.2020.123457 https://doi.org/10.1016/j.jhazmat.2020.123457
Publication status	Published - Jan 15 2021

Keywords

BiOBr
Photocatalyst
Doping
Antibiotic
bacteria
E. coli bacteria

ASJC Scopus subject areas

Pollution
Waste Management and Disposal
Health, Toxicology and Mutagenesis
Environmental Engineering
Environmental Chemistry

Access to Document

http://www.sciencedirect.com/science/article/pii/S0304389420314461

Cite this

Cho, E.-C., Chang-Jian, C.-W., Huang, J.-H., Lee, G.-Y., Hung, W.-H., Sung, M.-Y., Lee, K.-C., Weng, H. C., Syu, W.-L., Hsiao, Y.-S., & Chen, C.-P. (2021). Co²⁺-Doped BiOBr_xCl_1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli. Journal of Hazardous Materials, 402, 123457. Article 123457. https://doi.org/10.1016/j.jhazmat.2020.123457, https://doi.org/10.1016/j.jhazmat.2020.123457

Co²⁺-Doped BiOBr_xCl_1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli. / Cho, Er-Chieh; Chang-Jian, Cai-Wan; Huang, Jen-Hsien et al.
In: Journal of Hazardous Materials, Vol. 402, 123457, 15.01.2021, p. 123457.

Research output: Contribution to journal › Article › peer-review

Cho, E-C, Chang-Jian, C-W, Huang, J-H, Lee, G-Y, Hung, W-H, Sung, M-Y, Lee, K-C, Weng, HC, Syu, W-L, Hsiao, Y-S & Chen, C-P 2021, 'Co²⁺-Doped BiOBr_xCl_1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli', Journal of Hazardous Materials, vol. 402, 123457, pp. 123457. https://doi.org/10.1016/j.jhazmat.2020.123457, https://doi.org/10.1016/j.jhazmat.2020.123457

Cho EC, Chang-Jian CW, Huang JH, Lee GY, Hung WH, Sung MY et al. Co²⁺-Doped BiOBr_xCl_1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli. Journal of Hazardous Materials. 2021 Jan 15;402:123457. 123457. doi: 10.1016/j.jhazmat.2020.123457, 10.1016/j.jhazmat.2020.123457

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title = "Co2+-Doped BiOBrxCl1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli",

abstract = "In this article, we have synthesized Co2+-doped BiOBrxCl1-x hierarchical nanostructured microspheres, featuring different degrees of Co2+ doping, displaying excellent photocatalytic performance. X-ray diffraction and Raman spectroscopy indicated that the Co2+ ions were successfully doped into the BiOBrxCl1-x nanocrystals. The photodegradation rate of rhodamine B mediated by a doped BiOBrxCl1-x was 150 % greater than that of the non-doped BiOBr. We ascribe the improved photocatalytic capability of the Co2+-doped BiOBrxCl1-x to a combination of its superior degree of light absorption, more efficient carrier separation, and faster interfacial charge migration. The major active species involved in the photodegradation of RhB also has been investigated. Moreover, the doped BiOBrxCl1-x possessed excellent cellular biocompatibility and displayed remarkable performance in the photocatalytic bacterial inactivation.",

keywords = "BiOBr, Photocatalyst, Doping, Antibiotic, bacteria, E. coli bacteria",

author = "Er-Chieh Cho and Cai-Wan Chang-Jian and Jen-Hsien Huang and Guang-Yu Lee and Wei-Hung Hung and Ming-Yen Sung and Kuen-Chan Lee and Weng, {Huei Chu} and Wei-Lin Syu and Yu-Sheng Hsiao and Chih-Ping Chen",

note = "Funding Information: We thank the Ministry of Science and Technology (MOST) of Taiwan (grant nos.: MOST 108-2320-B-038-043 , MOST 108-2113-M-152-001 ) and CPC Corporation (grant no.: 105-3011 ) for financial support. We also thank Mr. Chi-Ming Lee for excellent technical support, and the Core Facility Center at Taipei Medical University. The research endeavors at Ming Chi University of Technology and National Taiwan University of Science and Technology were supported in part by the MOST of Taiwan (grant nos.: MOST 107-2221-E-131-009-MY3 , MOST 108-2221-E-131-004-MY3 ). Publisher Copyright: {\textcopyright} 2020 Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2021",

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doi = "10.1016/j.jhazmat.2020.123457",

language = "English",

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T1 - Co2+-Doped BiOBrxCl1-x hierarchical microspheres display enhanced visible-light photocatalytic performance in the degradation of rhodamine B and antibiotics and the inactivation of E. coli

AU - Cho, Er-Chieh

AU - Chang-Jian, Cai-Wan

AU - Huang, Jen-Hsien

AU - Lee, Guang-Yu

AU - Hung, Wei-Hung

AU - Sung, Ming-Yen

AU - Lee, Kuen-Chan

AU - Weng, Huei Chu

AU - Syu, Wei-Lin

AU - Hsiao, Yu-Sheng

AU - Chen, Chih-Ping

N1 - Funding Information: We thank the Ministry of Science and Technology (MOST) of Taiwan (grant nos.: MOST 108-2320-B-038-043 , MOST 108-2113-M-152-001 ) and CPC Corporation (grant no.: 105-3011 ) for financial support. We also thank Mr. Chi-Ming Lee for excellent technical support, and the Core Facility Center at Taipei Medical University. The research endeavors at Ming Chi University of Technology and National Taiwan University of Science and Technology were supported in part by the MOST of Taiwan (grant nos.: MOST 107-2221-E-131-009-MY3 , MOST 108-2221-E-131-004-MY3 ). Publisher Copyright: © 2020 Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2021/1/15

Y1 - 2021/1/15

N2 - In this article, we have synthesized Co2+-doped BiOBrxCl1-x hierarchical nanostructured microspheres, featuring different degrees of Co2+ doping, displaying excellent photocatalytic performance. X-ray diffraction and Raman spectroscopy indicated that the Co2+ ions were successfully doped into the BiOBrxCl1-x nanocrystals. The photodegradation rate of rhodamine B mediated by a doped BiOBrxCl1-x was 150 % greater than that of the non-doped BiOBr. We ascribe the improved photocatalytic capability of the Co2+-doped BiOBrxCl1-x to a combination of its superior degree of light absorption, more efficient carrier separation, and faster interfacial charge migration. The major active species involved in the photodegradation of RhB also has been investigated. Moreover, the doped BiOBrxCl1-x possessed excellent cellular biocompatibility and displayed remarkable performance in the photocatalytic bacterial inactivation.

AB - In this article, we have synthesized Co2+-doped BiOBrxCl1-x hierarchical nanostructured microspheres, featuring different degrees of Co2+ doping, displaying excellent photocatalytic performance. X-ray diffraction and Raman spectroscopy indicated that the Co2+ ions were successfully doped into the BiOBrxCl1-x nanocrystals. The photodegradation rate of rhodamine B mediated by a doped BiOBrxCl1-x was 150 % greater than that of the non-doped BiOBr. We ascribe the improved photocatalytic capability of the Co2+-doped BiOBrxCl1-x to a combination of its superior degree of light absorption, more efficient carrier separation, and faster interfacial charge migration. The major active species involved in the photodegradation of RhB also has been investigated. Moreover, the doped BiOBrxCl1-x possessed excellent cellular biocompatibility and displayed remarkable performance in the photocatalytic bacterial inactivation.

KW - BiOBr

KW - Photocatalyst

KW - Doping

KW - Antibiotic

KW - bacteria

KW - E. coli bacteria

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