Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction

Fu Yu Tsai; Bo Nan Lin; Ming Jie Chen; Chung Yuan Mou; Shiuh Tzung Liu

doi:10.1016/j.tet.2007.03.046

Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction

Fu Yu Tsai, Bo Nan Lin, Ming Jie Chen, Chung Yuan Mou, Shiuh Tzung Liu

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

A palladium bipyridyl complex anchored onto nanosized mesoporous silica MCM-41 catalyzed the cross-coupling of aryl iodides or bromides with Grignard reagents to provide the corresponding biaryls in high yields. The reaction proceeded smoothly with an equal molar amount of substrate and Grignard reagent in the presence of 0.2-0.02 mol % of catalyst in THF at 50 °C or under refluxing conditions. The catalyst prepared may be used in a very low percentage, recovered after reaction, and re-used.

Original language	English
Pages (from-to)	4304-4309
Number of pages	6
Journal	Tetrahedron
Volume	63
Issue number	20
DOIs	https://doi.org/10.1016/j.tet.2007.03.046
Publication status	Published - May 14 2007
Externally published	Yes

Keywords

Kumada-Corriu reaction
Mesoporous silica
Palladium bipyridyl complex
Recyclable catalyst

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tet.2007.03.046

Cite this

@article{fbcf74a2667d49c8b0df33afabb4d8e1,

title = "Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction",

abstract = "A palladium bipyridyl complex anchored onto nanosized mesoporous silica MCM-41 catalyzed the cross-coupling of aryl iodides or bromides with Grignard reagents to provide the corresponding biaryls in high yields. The reaction proceeded smoothly with an equal molar amount of substrate and Grignard reagent in the presence of 0.2-0.02 mol % of catalyst in THF at 50 °C or under refluxing conditions. The catalyst prepared may be used in a very low percentage, recovered after reaction, and re-used.",

keywords = "Kumada-Corriu reaction, Mesoporous silica, Palladium bipyridyl complex, Recyclable catalyst",

author = "Tsai, {Fu Yu} and Lin, {Bo Nan} and Chen, {Ming Jie} and Mou, {Chung Yuan} and Liu, {Shiuh Tzung}",

note = "Funding Information: The research was financially supported by the National Science Council of Taiwan (NSC94-2113-M-027-002).",

year = "2007",

month = may,

day = "14",

doi = "10.1016/j.tet.2007.03.046",

language = "English",

volume = "63",

pages = "4304--4309",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "20",

}

TY - JOUR

T1 - Anchored palladium bipyridyl complex in nanosized MCM-41

T2 - a recyclable and efficient catalyst for the Kumada-Corriu reaction

AU - Tsai, Fu Yu

AU - Lin, Bo Nan

AU - Chen, Ming Jie

AU - Mou, Chung Yuan

AU - Liu, Shiuh Tzung

N1 - Funding Information: The research was financially supported by the National Science Council of Taiwan (NSC94-2113-M-027-002).

PY - 2007/5/14

Y1 - 2007/5/14

N2 - A palladium bipyridyl complex anchored onto nanosized mesoporous silica MCM-41 catalyzed the cross-coupling of aryl iodides or bromides with Grignard reagents to provide the corresponding biaryls in high yields. The reaction proceeded smoothly with an equal molar amount of substrate and Grignard reagent in the presence of 0.2-0.02 mol % of catalyst in THF at 50 °C or under refluxing conditions. The catalyst prepared may be used in a very low percentage, recovered after reaction, and re-used.

AB - A palladium bipyridyl complex anchored onto nanosized mesoporous silica MCM-41 catalyzed the cross-coupling of aryl iodides or bromides with Grignard reagents to provide the corresponding biaryls in high yields. The reaction proceeded smoothly with an equal molar amount of substrate and Grignard reagent in the presence of 0.2-0.02 mol % of catalyst in THF at 50 °C or under refluxing conditions. The catalyst prepared may be used in a very low percentage, recovered after reaction, and re-used.

KW - Kumada-Corriu reaction

KW - Mesoporous silica

KW - Palladium bipyridyl complex

KW - Recyclable catalyst

UR - http://www.scopus.com/inward/record.url?scp=34047265359&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34047265359&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2007.03.046

DO - 10.1016/j.tet.2007.03.046

M3 - Article

AN - SCOPUS:34047265359

SN - 0040-4020

VL - 63

SP - 4304

EP - 4309

JO - Tetrahedron

JF - Tetrahedron

IS - 20

ER -

Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this