Aluminum-promoted tungstated zirconia catalyst in n-butane isomerization reaction

She Tin Wong, Tao Li, Soofin Cheng, Jyh Fu Lee, Chung Yuan Mou

Research output: Contribution to journalArticlepeer-review

40 Citations (Scopus)


The promotion effect of Al on tungstated zirconia (WZ) catalyst was studied in a butane isomerization reaction and compared with Fe-promoted catalyst (FWZ). XRD and EXAFS studies revealed an interaction between Al and WOx, whereas XANES analysis indicates that the octahedral symmetry around W sites remained unchanged. Two Al3+ sites are present on co-precipitated Al-promoted WZ (AWZC) catalyst; one is formed by the substitution of Al species in the WOx structure and the other is the terminal Al species anchoring on the WOx surface. Only the terminal Al3+ sites are evident in impregnated AWZ catalyst. Our NH 3-TPD and DRIFT results suggest that these Al3+ sites are Lewis acid in nature with at least moderate acid strength. They are stronger than those Brönsted and Lewis acid sites originally present in WO x. Exposure of the catalyst to atmospheric water results in the poisoning of these Al3+ sites by chemisorbed water, forming octahedral species. In an n-butane isomerization reaction, Al addition onto WZ increases both the activity and the stability of the catalysts. The catalytic activity of fresh catalysts decreases in the order FWZI>AWZ C≥WZC, whereas regenerated catalysts follow the order AWZC≥FWZI>WZC. The improved activity of AWZC over WZC catalyst is related to the increased acidity created by the Al promoter. Most importantly, a great enhancement in catalytic activity was observed for regenerated catalyst relative to the fresh catalyst. The regenerated AWZC catalyst is as active as the FWZ I catalyst.

Original languageEnglish
Pages (from-to)45-56
Number of pages12
JournalJournal of Catalysis
Issue number1
Publication statusPublished - Apr 1 2003
Externally publishedYes


  • Acid catalyst
  • Aluminum
  • Iron
  • Lewis acid site
  • NH-TPD
  • Promoter
  • Tungstated zirconia
  • n-Butane isomerization

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry


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